Plasmonic interactions in a well-defined array of metallic nanoparticles can lead to interesting optical effects, such as local electric field enhancement and shifts in the extinction spectra, which are of interest in diverse technological applications, including those pertaining to biochemical sensing and photonic circuitry. Here, we report on a single-step wafer scale fabrication of a threedi...

Materials with large chiral optical activity at visible wavelengths are of great interest in photonics, particularly as a route to chiral optical metamaterials. Here, we demonstrate the plasmonic enhancement of the chiral optical activity of chiral poly(fluorene-alt-benzothiadiazole) (PFBT) doped with gold nanoparticles. The supramolecular helical organization of polymeric chains with simultane...

Plasmon interactions are a subject of great interest from both the technological as well as the fundamental points of view. In this Perspective, we outline the great variety of physical phenomena that are produced by the interactions of localized surface plasmon resonance with molecular excitons; with other plasmonic nanostructures, particularly the Fano effect; and with nonplasmonic nanopartic...

The catalytic and optical properties of metal nanoparticles can be combined to create platforms for light-driven chemical energy storage and enhanced in-situ reaction monitoring. However, the heavily damped plasmon resonances of many catalytically active metals (e.g. Pt, Pd) prevent this dual functionality in pure nanostructures. The addition of catalytic metals at the surface of efficient plas...

We demonstrate theoretically the trapping and manipulating of a gold nanoparticle dimer, using surface plasmon excited by a focused linearly-polarized laser beam on a silver film. We use both finite-difference time-domain force analysis and Maxwell stress tensor to show that the gold nanoparticle dimer can be trapped by a virtual probe pair. A formula is derived to represent the plasmonic field...

The electrocatalytic properties of nanoparticles depend on their size, shape and composition. These properties are typically probed by measuring the total electrocatalytic reaction current of a large number of nanoparticles, but this approach is time-consuming and can only measure the average catalytic activity of the nanoparticles under study. However, the identification of new catalysts requi...

Utilizing boundary integral method (BIM), we investigate molecularspontaneous emission rate enhancement in the vicinity of plasmonic nanoparticles ofelliptical cross section. These types of nanoparticles can considerably enhance themolecule decay rate. The spontaneous emission rate can be modified by altering theaspect ratio of the elliptical nanoparticle, the background refractive index andnan...

We describe and demonstrate a general strategy for engineering binary and ternary hybrid nanoparticles based on spontaneous epitaxial nucleation and growth of a second and third component onto seed nanoparticles in high-temperature organic solutions. Multifunctional hybrid nanoparticles that combine magnetic, plasmonic, and semiconducting properties and that are tunable in size and morphology c...

Cationic gold nanoparticles offer intriguing opportunities as drug carriers and building blocks for self-assembled systems. Despite major progress on gold nanoparticle research in general, the synthesis of cationic gold particles larger than 5 nm remains a major challenge, although these species would give a significantly larger plasmonic response compared to smaller cationic gold nanoparticles...