Thermally stable nanoarchitectures are realized on the Ag(100) surface by self-assembly of asymmetrically substituted arenes. The process is instigated by adsorption-induced molecule → surface charge transfer that gives rise to in-plane dipole moments. Observation and calculation indicate that cooperative interactions further enhance the stability of these polarizable systems.

The title compound, C(48)H(43)N(7), is a polyaza-polycyclic compound with a near-C(2) symmetric skeleton. In the crystal, a N-H⋯π inter-action occurs.

The synthesis of O-doped benzorylenes, in which peripheral carbon atoms have been replaced by oxygen atoms, has been achieved for the first time. This includes key high-yielding ring-closure steps which, through intramolecular C-O bond formation, allow stepwise planarization of oligonaphthalenes. Single-crystal X-ray diffraction showed that the tetraoxa derivative forms remarkable face-to-face ...

BACKGROUND: Polycyclic aromatic hydrocarbons (PAHs) represent a group of organic compounds containing two or more aromatic rings. Their control in the human food chain is required due to the mutagenic and carcinogenic potential, exhibited in vertebrates. In the present study, the occurrence of PAHs in 36 cheeses smoked by various processes was investigated. RESULTS: PAH concentrations (sum of 1...

Recently sorption of organic pollutants, in particular polycyclic aromatic hydrocarbons (PAHs), has received much attention and researchers agree that organic matter (the amount of organic matter and its nature) is the most important factor affecting the sorption, desorption and fate of organic pollutants in soil and sediments. It is well documented that organic matter of soil and sediments is ...