Synthesis of poly(2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.

a r t i c l e i n f o Elastic properties of soft, three-dimensional dimers, interacting through site-site n-inverse-power potential, are determined by computer simulations at zero temperature. The degenerate crystal of dimers exhibiting (Gaussian) size distribution of atomic diameters – i.e. size polydispersity – is studied at the molecular number density 1= ffiffiffi 2 p ; the distance between...

The recently proposed universal relations between the moments of the polydispersity distributions of a phase-separated weakly polydisperse system are analyzed in detail using the numerical results obtained by solving a simple density functional theory of a polydisperse fluid. It is shown that universal properties are the exception rather than the rule.

Numerous vibrational modes of spherical submicrometer particles in fabricated soft opals are experimentally detected by Brillouin light scattering and theoretically identified by their spherical harmonics by means of single-phonon scattering-cross-section calculations. The particle size polydispersity is reflected in the line shape of the low-frequency modes, whereas lattice vibrations are prob...

4 Analysis of Small Angle Scattering Data 10 4.1 Model Independent Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 4.1.1 The Scattering Invariant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 4.1.2 Porod Scattering . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 4.1.3 Guinier Analysis . . . . . . . . . . . . . . . . . . . . . ....

Core cross-linked star polymers of low polydispersity were efficiently prepared in high yield by RAFT-mediated emulsion and dispersion polymerizations in water at high solid content. These star polymers were demonstrated to be effective emulsifiers, and the emulsion was successfully used as template to fabricate polymer particles.

Aspects of polarized coherent quasi-elastic scattering by dilute macromolecular solutions are discussed. Effects of polydispersity, branching and chain stiffness are considered, particularly in respect to the observable first cumulant of the dynamic structure factor and its dependence on the scattering angle. A combination of integrated and time-resolved scattering data yields the maximum infor...

By extending the nonequilibrium potential refinement algorithm and lattice switch method to the semigrand ensemble, the semigrand potentials of the fcc and hcp structures of polydisperse hard-sphere crystals are calculated with the bias sampling scheme. The result shows that the fcc structure is more stable than the hcp structure for polydisperse hard-sphere crystals below the terminal polydisp...