This study investigates the in vitro cytocompatibility of one-dimensional and two-dimensional (1D and 2D) carbon and inorganic nanomaterial reinforced polymeric nanocomposites fabricated using biodegradable polymer poly (propylene fumarate), crosslinking agent N-vinyl pyrrolidone (NVP) and following nanomaterials: single and multiwalled carbon nanotubes, single and multiwalled graphene oxide na...

Polymer electrolyte fuel cell (PEFC) membranes are subject to radical-induced degradation. Antioxidant strategies for hydrocarbon-based ionomers containing aromatic units can focus on intermediates that formed upon attack by hydroxyl radicals (HO · ). Among the different intermediates, cation radical P ·+ is most promising target repair, example cerium(III). For “repair” reaction of Ce(III) wit...

Polymer nanofiber based materials have been widely investigated for use as tissue engineering scaffolds. While promising, these materials are typically fabricated through techniques that require significant time or cost. Here we report a rapid and cost effective air-brushing method for fabricating nanofiber scaffolds using a simple handheld apparatus, compressed air, and a polymer solution. Air...

Ageing and stabilization polymers is a major part of materials science. Aging of polymers defined as a set of chemical and physical transformations, leads to the loss of their set the desired properties. The main role in these transformations belong to chemical processes of degradation and crosslinking of macromolecules. Processes decomposition and structuring polymer conjugates include radical...

Degradation is a common problem for polymer matrix composites (PMCs) under low thermal cycling conditions. This paper investigates the effects of low thermal cycling on total mass loss (TML) and surface degradation of PMCs. Unnotched and open-hole specimens were weighed before and after low thermal cycling. The total mass loss and surface degradation of the specimens were studied over 250 cycle...

Biodegradable polymers have great number of applications in modern reconstructive medicine and orthopaedics. One of them is manufacturing of tissue engineering scaffolds, which are potential analogues of bone grafts. Bone scaffolds are commonly used to support reconstruction of tissue losses caused by injury or disease. The main goal of using the tissue engineered scaffolds is to maintain the m...

A degradation study of polystyreneepolybutadieneepolystyrene and polyisopreneepolystyrenee polyisoprene in both dichloromethane and hexane solvents is presented. Alternative solvents for metathetic degradation provide the potential for greener chemistry, better selectivity, and control over the products. The catalyst concentration and solvent selection both determine the products formed. The de...

The synthesis of a series of novel, water-soluble poly(organophosphazenes) prepared via living cationic polymerization is presented. The degradation profiles of the polyphosphazenes prepared are analyzed by GPC, 31P NMR spectroscopy, and UV-Vis spectroscopy in aqueous media and show tunable degradation rates ranging from days to months, adjusted by subtle changes to the chemical structure of th...