In this paper, we demonstrate a monolithic integrated micro direct methanol fuel cell (μDMFC) for the first time. The monolithic integrated μDMFC combines proton exchange membrane (PEM) and Pt nanocatalysts, in which PEM is achieved by the functionalized porous silicon membrane and 3D Pt nanoflowers being synthesized in situ on it as catalysts. Sulfo groups functionalized porous silicon membran...

These recommendations aim to be a tool for the selection and appraisal of the methods of characterization of porous solids, and to also give the warnings and guidelines on which the experts generally agree. For this purpose, they successively consider the description of a porous solid (definitions, terminology), the principal methods available (stereology , radiation scattering, pycnometry, ads...

In this work, we present a facile and low-cost approach to synthesize heteroatom doped porous carbon via hydrothermal treatment of stem bark of broussonetia papyrifera (BP) as the biomass precursor in diluted sulfuric acid, and following thermal activation by KOH at 800 °C. The morphology, structure and textural property of the prepared porous carbon (PC) are investigated by scanning electron m...

Edited by Reed M. Izatt. © 2016 John Wiley & Sons, Ltd. Published 2016 by John Wiley & Sons, Ltd. Inorganic zeolites [1], mesoporous silica [2], and porous carbon [3] are useful materials because of their permanent porosity imparted by their architectural stability in the absence of guest molecules. The chemical functionalization and structure control of these classes of porous materials have b...

The primary objective of this paper was to synthesize a porous calcium silicate hydrate (CSH) with enhanced phosphate recovery property using polyethyleneglycol (PEG) as pore-generation agent. The formation mechanism of porous CSH was proposed. PEG molecules were inserted into the void region of oxygen-silicon tetrahedron chains and the layers of CSH. A steric hindrance layer was generated to p...

The heat and mass transfer phenomena that occur in beds of ventilated hygroscopic porous media are coupled. This results in two transfer waves traversing bulks of porous medium that initially have a uniform temperature and moisture content, and that are subsequently ventilated with air that is not in thermodynamic equilibrium with the solids. The more rapidly travelling wave is known as a tempe...

Solid Freeform Fabrication processes such as three-dimensional printing (3DP) and selective laser sintering (SLS) produce porous parts that must be densified. New steel infiltration methods can produce parts of standard alloy compositions with properties comparable to wrought materials. However, the infiltration process introduces dimensional errors due to both shrinkage and creep—particularly ...

We present vapor-liquid phase coexistence curves for binary fluid mixtures in a disordered porous solid. The porous material is modeled as a collection of randomly dispersed hard spheres. A variant of the Monte Carlo Gibbs ensemble method [J. K. Brennan and W. Dong, J. Chem. Phys. 116, 8948 (2002)] is used to simulate Lennard-Jones fluid mixtures at several porosities: 0.9, 0.95, and 0.975. Eff...

Porous alumina films formed by aluminum anodic oxidation have been intensively studied to use them as molds to form nanowires or dots. Recently we established the formation of porous alumina on solid substrates such as Si, and found a formation of an ordered aluminum hexagonal dot array after finishing of anodic oxidation on a SiO2 substrate. We investigated AFM nanoindentation to control the i...

The theories of porous materials represent a material length scale and are quite sufficient for a large number of the solid mechanics applications. In the following, we restrict our attention to the behavior of the porous solids in which the matrix material is elastic and the interstices are voids of material. The intended applications of this theory are to the geological materials, like rocks ...