Thermooxidative degradation of poly(vinyl chloride) (PVC) is inevitable during processing of PVC. Recycling of this polymer requires reprocessing in most of the cases, and due to the low thermal stability of PVC, it is of paramount importance to reveal the effect of thermooxidation on the thermal stability of this commercially important polymer. However, detailed systematic investigations are l...

Submit Manuscript | http://medcraveonline.com PVC has significant defects due to its quick decomposition at temperature higher than 130°C [3-5]. This process results in a significant change in color, reducing the mechanical properties and the generated HCl exacerbates the decomposition of PVC, so the usage of PVC thermal stabilizers is inevitable [4,6]. Our group had synthesized pentaerythritol...

A highly selective electrode for Bromide ion based on aza pyrilium derivative as an excellentionophore is described.The sensor exhibits a good linear response with a slope of ( 60±1 ) mV per decadeover the concentration range of ( 1×10-3 – 9×10-6 M ) , and a detection limit of ( 3×10-6 M ) of Bromideions .The electrode response is independent of pH in the range of(4.0 –9.5).Selectivity coeffici...

This research verified the applicability and effectiveness of the ultrasonic monitoring of sediments stuck on the inner wall of polyvinyl chloride (PVC) pipes. For identifying the transmittance of acoustic energy and the speed of sound in the PVC material, the pulse-echo ultrasonic testing was conducted for PVC sheets of different thicknesses. To simulate the solidified sediment, the hot melt a...

This paper presents an approach to the suppression of the emission of dioxin and its precursors as a result of the co-incineration of poly (vinyl chloride) (PVC) with TiO2-encapsulating polystyrene (TEPS), in which TiO2 nanoparticles with the capacity to adsorb dioxin and its precursors are encapsulated without significant agglomeration. Field-emission scanning electron microscopy (FE-SEM) and ...

Submit Manuscript | http://medcraveonline.com PVC has significant defects due to its quick decomposition at temperature higher than 130°C [3-5]. This process results in a significant change in color, reducing the mechanical properties and the generated HCl exacerbates the decomposition of PVC, so the usage of PVC thermal stabilizers is inevitable [4,6]. Our group had synthesized pentaerythritol...

Current fundamental researches in the field of potentiometry demonstrate perspectives using polymeric nanostructured materials as ion-to-electron transducers Solid-Contact Potentiometric Sensors (SCSs). This paper reports preparation and comparative study plasticized Poly(Vinyl Chloride) (PVC) membranes modified with fullerene C60, single-walled carbon nanotubes SWCNTs, multiwalled nanotubes, g...

BACKGROUND Polyvinyl chloride (PVC) plasticized with di(2-ethylhexyl) phthalate (DEHP) is commonly used for blood collection and storage. DEHP has protective effects on RBC membranes, but is also a toxin. METHODS A paired study was conducted to investigate the influence of DEHP and two alternative plasticizers, 1,2-cyclohexane-dicarboxylic acid diisononyl ester (DINCH) and n-butyryl-tri-n-hex...

The development of ion-selective microelectrodes for monitoring lithium ions in blood or serum is very important in the field of clinical chemistry. For this interest, all-solid-state microsensors based on impedance measurement for the detection of Li+ has been developed. The selective PVC membrane composition used was obtained by dissolving 1.2 % (w/w) Lithium ionophore III, 66 % (w/w) o-nitro...

BACKGROUND Polyvinyl chloride (PVC) materials have been linked to asthma in several epidemiologic studies, but the possible causal factors remain unknown. PARTICIPANTS We challenged 10 subjects experimentally to degraded PVC products under controlled conditions. All of the subjects had previously experienced respiratory symptoms suspected to be caused by this kind of exposure in their work pl...