In this article several control schemes for a pilot scale polymerization reactor are proposed and one of them is selected as the most suitable design. The performances of proposed schemes have been compared through computer simulations. The controllers are PID and Chosen reaction is polymerization of methyl methacrylate which is highly exothermic.

in the present work, a titanium-based ziegler-natta catalyst was employed to synthesize ultra molecular weight polyethylene in a slurry medium. the effect of different parameters such as ethylene pressure, temperature, catalyst composition, and hydrogen pressure was studied. as the results indicate, increasing either [al]/[ti] ratio or temperature causes polymerization rate to go through a maxi...

atom transfer radical polymerization of styrene (st) and methyl methacrylate (mma) was performed at 90oc in the absence and presence of nanoclay (cloisite 30b). trichloromethyl-terminated poly(vinyl acetate) telomerand cucl/ pmdeta were used as a macroinitiator and catalyst system, respectively. the experimental results showed that the atom transfer radical polymerization of st and mma in the a...

this research was performed to study the effect of murray red gum tree age (4, 6, 8 years) on the chemical components, viscosity and the cellulose degree of polymerization. the eucalyptus trees were cut at the ages of 4, 6, and 8 from hand planted forests. the contents of cellulose, hemicellulose, lignin, extractives and ash for each age were then determined. the results show that with increasi...

polyvinyl ester green composites were synthesized with walnut shell powder (wsp) by in-situ polymerization technique. the green composites have been evaluated for mechanical properties such as tensile strength, tensile modulus and hardness. sliding wear loss, specific wear rate and coefficient of friction were investigated by using computerized pin-on–disc machine at normal applied loads of 20,...

The kinetics of o/w electrostatically and sterically-stabilized microemulsion polymerization of styrene with and without macromonomeric azoinitiator (macroinimer; MIM) have been investigated. The microemulsion polymerization stabilized by the ionic emulsifier sodium dodecyl sulfate (SDS) or the non-ionic emulsifier Tween 20 (Tw 20) was initiated by ammonium peroxodisulfate (APS)/sodium thiosulf...

The pseudo-octahedral molybdenum benzylidyne complex [TolC≡Mo(ONO)(OR)]·KOR (R = CCH3(CF3)2) 1, featuring a stabilizing ONO pincer ligand, initiates the controlled living polymerization of strained dibenzocyclooctynes at T > 60 °C to give high molecular weight polymers with exceptionally low polydispersities (PDI ∼ 1.02). Kinetic analyses reveal that the growing polymer chain attached to the pr...

This article introduces tri-cationic hemicyanine dye employed as a visible-light photoinitiator of acrylic monomers polymerization. This dye, in combination with borate anions, was found to be a very effective photoinitiating system. The kinetics of trimethylolpropane triacrylate polymerization was studied by a microcalorimetric method. The photoredox pair concentration, the co-initiator struct...