reaction constants and heat release during thermophilic aerobic digestion of typical secondary and mixed sludges were determined. maximum reaction constant, determined by measuring the amounts of biodegradable volatile suspended solids (bvss) removed, occurred in the temperature range of 55-60 ºc. measurement of heat releases were carried out, at the same range, by the aid of a temperature prog...

The concept of nonthermal microwave effects has received considerable attention in recent years and is the subject of intense debate in the scientific community. Nonthermal microwave effects have been postulated to result from a direct stabilizing interaction of the electric field with specific (polar) molecules in the reaction medium that is not related to a macroscopic temperature effect. In ...

Experiments designed to simulate the low temperature surface chemistry occurring in interstellar clouds provide clear evidence of a reaction between oxygen atoms and propyne ice. The reactants are dosed onto a surface held at a fixed temperature between 14 and 100 K. After the dosing period, temperature programmed desorption (TPD), coupled with time-of-flight mass spectrometry, are used to iden...

background heat is a harmful factor in workplaces that causes physiologic and cognitive changes in workers. objectives the purpose of this study was to investigate the effect of cooling vest on heat strain and reaction time while wearing chemical-biological-nuclear protective clothes. methods twelve male students with mean age of 25 ± 2 and body mass index (bmi) of 23 ± 1.5 were recruited in th...

some amide derivatives have been synthesized by the reaction of corresponding nitriles with potassium tert-butoxide as a nucleophilic oxygen source under ultrasonic irradiation. this new methodology provides good to excellent yields in short reaction times (15-90 min) at room temperature.

a convenient synthesis of different types of polyfunctional dihydropyrrol-2-ones via one-pot four component reactions of formaldehyde, dialkyl acetylenedicarboxylates and amines, catalyzed by trichloroacetic acid (cl3cco2h) at room temperature has been investigated. the significant advantages of this synthetic method are mild reaction conditions, available and inexpensive material, short reacti...

Hydrolysis of α-cellulose by H2SO4 is a heterogeneous reaction. As such the reaction is influenced by physical factors. The hydrolysis reaction is therefore controlled not only by the reaction conditions (acid concentration and temperature) but also by the physical state of the cellulose. As evidence of this, the reaction rates measured at the high-temperature region (above 200°C) exhibited a s...

in this work, thermal degradation behavior of a fuel-rich energetic mixture containing epoxy binder was studied by thrmogravimetric analysis and differential scanning calorimetry under dynamic nitrogen atmosphere at different heating rates. variation of the thermal degradation activation energy of the mixture was evaluated by differential and integral isoconversional methods via akts software p...

magnetite (fe3o4) nanoparticles have been successfully prepared by a novel one-step and surfactant-free approach utilizing ferrous ion, as a single iron source. in this manner, the reaction occurs between two aqueous solutions via the spontaneous transfer of ammonia gas from one to another in room temperature. no ferric source or oxidizing specie, oxidation controlling and capping agents are ne...

A point-of-care, diagnostic system incorporating a portable thermal cycler and a compact fluorescent detector for real-time, polymerase chain reaction (PCR) on disposable, plastic microfluidic reactors with relatively large reaction volume (ranging from 10 µL to 100 µL) is described. To maintain temperature uniformity and a relatively fast temperature ramping rate, the system utilizes double-si...