Two types of lithographic methods were used to modify GaP(100) surfaces with commercially available alkanethiol molecules: microcontact printing (lCP) and ‘‘dip-pen” nanolithography (DPN). The patterned surfaces were characterized by atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS). The characteriz...

Methanol decomposition and oxidation on Pd(111) at millibar pressure were studied by in situ polarization-modulation infrared reflection absorption spectroscopy (PM-IRAS), on-line gas chromatography and pre- and postreaction X-ray photoelectron spectroscopy (XPS). Various dehydrogenation products such as methoxy CH3O, formaldehyde CH2O, formyl CHO, and CO could be spectroscopically identified. ...

The characterization of fractures is of vital importance for studies in many industries. In the present work, we used terahertz reflection measurements to identify simulated gaps of different widths that resemble fractures. The time interval between pulses (Δt) was proportional to the distance between the interfaces. In addition, fast Fourier transform (FFT) corresponding to the waveforms was a...

Optical properties and the geometric structure of self-assembled monolayers of azobenzene-functionalized alkanethiols have been investigated by UV/visible and near edge X-ray absorption fine structure spectroscopy in combination with density-functional theory. By attaching a trifluoro-methyl end group to the chromophore both the molecular tilt and twist angle of the azobenzene moiety are access...

Pd supported on ZnO has recently raised great interest as a catalyst for methanol steam reforming. Different from unsupported Pd, Pd-ZnO shows high selectivity and good conversion towards CO2 and hydrogen [1]. The difference is attributed to the formation of a PdZn alloy under reaction conditions, but there is still limited knowledge on the exact surface structure/composition and reaction mecha...

Matching pairs of tumor and non-tumor kidney tissue samples of four patients were investigated ex vivo using a combination of two methods, attenuated total reflection mid infrared spectroscopy and fluorescence spectroscopy, through respectively prepared and adjusted fiber probes. In order to increase the data information content, the measurements on tissue samples in both methods were performed...

The adsorption of molybdenum hexacarbonyl on thin dehydroxylated alumina films grown on an Mo(100) single-crystal substrate is studied in ultrahigh vacuum using primarily temperature-programmed desorption and reflection-absorption infrared spectroscopy. Subcarbonyls are detected using infrared spectroscopy at low temperatures and desorb at 245K. A portion of the subcarbonyls decomposes to form ...

Noble metal Ag nanoparticles with unique surface plasmon resonance property have attracted much attention recently in the field of photocatalysis. Based on the advantages of Ag nanoparticles and semiconductor CeO2, a novel plasmonic photocatalyst Ag-AgCl/CeO2 was prepared with a facile route. The as-prepared samples were characterized using scanning and transmission electron microscopy, X-ray p...

Atmospheric corrosion, the most common form of metal corrosion, occurs within the interfacial region between a solid, and the surrounding atmosphere. In fact three phases and two interfaces are involved: the gas, a thin liquid layer, a solid, the gas/liquid and the liquid/solid interfaces. In this thesis, the vapor/liquid and liquid/metal interfaces have been studied by the in-situ techniques v...

We demonstrate interstitial diffuse optical time-of-fight spectroscopy based on a single fiber for both light delivery and detection. Detector saturation due to the massive short-time reflection is avoided by ultrafast gating of a single photon avalanche diode. We show that the effects of scattering and absorption are separable and that absorption can be assessed independently of scattering. Me...