An unexpected doubling in redox storage emerging from a new pincer ligand upon bis-ligation of iron(ii) is described. When tetrazine arms are present at the two ortho positions of pyridine, the resulting bis-tetrazinyl pyridine (btzp) pincer ligand displays a single one-electron reduction at ca. -0.85 V vs. Ag/AgCl. Complexation to iron, giving the cation Fe(btzp)2(2+), shows no oxidation but f...

We conducted an experiment to determine whether the rhythm with which imagined syllables are produced may be decoded from EEG recordings. High density EEG data were recorded for seven subjects while they produced in imagination one of two syllables in one of three different rhythms. We used a modified second-order blind identification (SOBI) algorithm to remove artefact signals and reduce data ...

The influence of the choice of the exchange-correlation functional (semilocal gradient corrected or hybrid functionals) on the electronic properties of metal-exchanged zeolites has been investigated for Cu- and Co-exchanged chabazite. The admixture of exact exchange in hybrid functionals increases the fundamental gap of purely siliceous chabazite, leading to better agreement with experiment and...

The electronic spectra of cold protonated aromatic amines: anilineH(+) C6H5-NH3(+), benzylamineH(+) C6H5-CH2-NH3(+) and phenylethylamineH(+) C6H5-(CH2)2-NH3(+) have been investigated experimentally in a large spectral domain and are compared to those of their hydroxyl homologues. In the low energy region, the electronic spectra are similar to their neutral analogues, which reveals the ππ* chara...

near-fault ground motions with long-period pulses can place severe demands on structures near an active fault. these pulse-type ground motions can be represented by pulse sequences with simple shapes. half-sinusoidal pulse sequences are used to approximate recorded ground motions and dynamic responses of sdof system under the excitation of these pulse sequences are studied. four cases are consi...

This study introduces a new method for determining the spectral response of a photovoltaic (PV) device. Instead of illuminating the PV device under test with monochromatic beams at different wavelengths, the device is irradiated with different broadband spectra. Variations in the spectra are made by employing different types of polychromatic filters. The advantage of using these types of filter...

Toxicity bioassays are important tools to determine biological effects of chemical agents on species. The questions remained on, what effects have been imposed on each of the different molecular site of cells by chemical exposure and how to find a pattern for chemical toxicity. To address the questions, HepG2 cell lines were exposed to the different concentrations of cisplatin for 24 hours to r...

In this paper a novel anti-reflection (AR) coating based on silicon nano-bars is designed and its impact on the performance of crystalline silicon (c-Si) thin-film solar cells is extensively studied. Silicon nano-bars with optimized size and period are embedded on top of the active layer, under a 100nm Si3N4 layer. As a result of the proposed layer stack, an inhomogeneous intermediate layer wit...

ft-raman spectra of saffron (crocus sativus l.) with a partial assignment is reported. based on the raman data, it is concluded that main pigments in saffron are crocins and crocetin. it is proposed that the quickly attainable ft-raman spectrum of solid saffron, may be used as a means of saffron standardization.