نتایج جستجو برای: ring inversion

تعداد نتایج: 164449  

2015
Chiara Venturini Nicolas Ratel-Ramond Andre Gourdon

In the title compound, C9H6O2, the carb-oxy-lic acid group is almost in the plane of the benzene ring, making a dihedral angle of 2.49 (18)°. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds, forming classical acid-acid inversion dimers, with an R 2 (2)(8) ring motif. The dimers are linked by pairs of C-H⋯O hydrogen bonds forming chains, enclosing R 2 (2)(16) ring motifs, ...

2013
Lei Wen Yimin Hu

In the title compound, C26H22N2O, one phenyl ring, one five-membered N-heterocyclic ring and one six-membered carbocyclic ring make up the hexa-hydro-benzo[f]iso-indole core. Another phenyl group is attached to the heterocyclic N atom as a substituent. The non-aromatic five- and six-membered rings both exhibit boat conformations. In the crystal, weak C-H⋯O and C-H⋯N inter-actions establish the ...

2012
Hoong-Kun Fun Chin Wei Ooi M. Sapnakumari B. Narayana B. K. Sarojini

In the title compound, C(17)H(15)FN(2)O, the pyrazoline ring adopts a flattened envelope conformation. The dihedral angle between the fluoro-substituted benzene ring and the phenyl ring is 69.20 (5)°. In the crystal, a pair of C-H⋯O hydrogen bonds link neighbouring mol-ecules, forming an inversion dimer. The crystal structure is further consolidated by C-H⋯π inter-actions and by a π-π inter-act...

2010
Yu-Xia Da Zheng-Jun Quan

In the title compound, C(14)H(9)NO(2), the dihedral angle between the pyridine ring and the lactone ring is 10.40 (3)°. The coumarin ring system is nearly planar, with a dihedral angle of 1.40 (2)° between the lactone and benzene rings. An intra-molecular C-H⋯O hydrogen bond occurs. In the crystal, inversion dimers linked by pairs of C-H⋯O inter-actions occur, generating R(2) (2)(14) loops.

2011
Hoong-Kun Fun Madhukar Hemamalini Hatem A. Abdel-Aziz Tarek Aboul-Fadl

In the title compound, C(17)H(16)N(6)O(2)S, an intra-molecular N-H⋯O inter-action generates an S(6) ring. The pyridine ring makes a dihedral angle of 71.38 (11)° with the thio-phene ring. In the crystal, mol-ecules are linked by a pair of N-H⋯N hydrogen bonds, forming an inversion dimer. The dimers are stacked in columns along the b axis through weak inter-molecular C-H⋯N hydrogen bonds.

2013
B. C. Manjunath S. Madan Kumar K. S. Vinay Kumar M. Prabhuswamy M. P. Sadashiva N. K. Lokanath

In the title compound, C28H18N2O5, the dihedral angle between the terminal benzoate rings is 20.67 (12)°. The central oxadiazole ring is almost coplanar with its two benzene ring substituents, making dihedral angles of 4.80 (16) and 5.82 (16)°. In the crystal, pairs of C-H⋯O hydrogen bonds form inversion dimers with R 2 (2)(40) ring motifs. The structure also features C-H⋯O, C-H⋯π and π-π inter...

2013
Youssef Kandri Rodi Amal Haoudi Frédéric Capet Ahmed Mazzah El Mokhtar Essassi Lahcen El Ammari

The fused imidazole and pyridine rings in the title compound, C13H10BrN3O, are linked to a benzyl group. The fused ring system is essentially planar, the largest deviation from the mean plane being 0.006 (2) Å. The phenyl ring is not coplanar with the fused ring system, as indicated by the dihedral angle of 67.04 (12)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds, for...

2011
Wei-Jin Gu Jin Zhuang Yu-Liang Jiang Bing-Xiang Wang

The title compound, C(18)H(15)NO(3), consists of an indolizine ring system and an aromatic ring. The two ring systems are not coplanar, the dihedral angle between the two being 54.26 (7)°. In the crystal, inversion dimers are formed by weak C-H⋯O interactions. These dimeric groups are further extended to form a regular two-dimensional structure by additional weak C-H⋯O inter-actions.

2009
Ming-Yang He Chao Li Xu-Jie Yang Lu-De Lu Xin Wang

The title compound, C(20)H(14)F(4)N(4), is a flexible bis-pyridine-type ligand with an extended fluorinated spacer group between the two pyridyl functions. The centroid of the central aromatic ring is situated on a crystallographic center of inversion. The dihedral angle between the pyridine ring and the central benzene ring is 63.85 (9)°. The crystal structure exhibits inter-molecular C-H⋯F hy...

2010
Narsimha Reddy Penthala Joshua Eldridge Thirupathi Reddy Yerram Reddy Sean Parkin Peter A. Crooks

In the title compound, C(22)H(20)N(+)·I(-), the dihedral angles between the central pyridine ring and two outer benzene rings are 15.30 (10) and 11.82 (11)°. There are inter-molecular π-π stacking inter-actions between the nearest phenyl ring over an inversion-related pyridyl ring, the shortest centroid-centroid distance being 3.672 (3) Å. The crystal structure of the compound indicates the 2,6...

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