Propylene oxide is a crucial feedstock in the plastic industry. The direct epoxidation of propylene using O2 considered among most promising means producing oxide. Here we report an integrated photo-electro-heterogeneous catalytic system for with O2. Bismuth vanadate (or TiO2) photocatalyst and Co-based electrocatalyst produces H2O2. A titanium silicalite-1 heterogeneous catalyst subsequently e...

Zeolite crystals offering a short diffusion pathway through the pore network are highly desired for number of catalytic and molecule separation applications. Herein, we develop simple synthetic strategy toward reducing thickness along b-axis MFI-type crystals, thus providing path straight channel. Our approach combines preliminary aging fluoride-assisted low-temperature crystallization. The syn...

Zeolite-supported single-atom catalysts (SACs) have emerged as a novel class of cheap and tuneable that can exhibit high activity, selectivity stability. In this work, we conduct an extensive screening by means density functional theory calculations to determine the usefulness 3d, 4d 5d transition metal (TM) SACs-supported in MFI-type Silicalite-1 zeolite for CO2 conversion. Two reaction mechan...