PURPOSE The purpose of this study was to compare the linear sintering behavior of presintered zirconia blocks of various densities. The mechanical properties of the resulting sintered zirconia blocks were then analyzed. MATERIALS AND METHODS Three experimental groups of dental zirconia blocks, with a different presintering density each, were designed in the present study. Kavo Everest® ZS bla...

The p-accepting character of a terminal carbide complex acting as a ligand is demonstrated experimentally and corroborates earlier theoretical predictions. As a result, coordination of a terminal ruthenium carbide complex to electron-rich metal centres is shown to provide a facile and versatile route to carbidebridged heterometallic complexes. Synthesis, reactivity, spectroscopic and structural...

Sintering with low frequency rf power (-50 M H z ) is a new technique with unique capabilities that has been used to sinter a variety of ceramic materials, including zirconia-toughened alumina, alumina, silicon carbide, and boron carbide. Processing with low frequencies offers many advantages compared to processing with conventional microwave frequencies (915 MHz and 2.45 GHz). Because of the l...

Silicon Carbide as an inorganic material possesses properties like high thermochemical stability, high hardness and fracture toughness, low thermal expansion coefficient etc. It is therefore, widely used in the making of refractory, semiconductor devices, combustion engines, etc. Being a nonoxide, it has a tendency to get oxidized at elevated temperature under oxidizing atmosphere. Oxidation of...

Zirconium carbide nanoparticles were produced by wire explosion process by exploding zirconium conductor in methane ambiance. X-ray diffraction studies of the particles produced by wire explosion process confirm the formation of cubic zirconium carbide particles. The results of the study indicates that unreacted zirconium content in the zirconium carbide powder could be reduced by exploding the...

Niobium Carbide (NbC) based cermet is a relatively less explored wear resistant material which has potential applications in moulds for ceramic injection moulding as well cutting tool inserts. The NbC-Ni cermets exhibit similar hardness WC-Co cemented carbide but show better resistance and chemical stability against iron or steel. demand Ni bonded NbC forecasted to increase due the rising cost ...

The first direct evidence is provided for the presence of an interstitial carbide in the Fe-V cofactor of Azotobacter vinelandii vanadium nitrogenase. As for our identification of the central carbide in the Fe-Mo cofactor, we employed Fe Kβ valence-to-core X-ray emission spectroscopy and density functional theory calculations, and herein report the highly similar spectra of both variants of the...

One of the ways to increase strength and reliability building structures is use steel – fibre reinforced concrete. Steel concrete has significant advantages over conventional A high degree resistance cracking contributes an in such physical mechanical parameters as compressive, tensile bending strength, water resistance, frost chemical penetration. In concrete, used a reinforcing material, even...

Metal matrix composites have been widely studied in terms of abrasion resistance, but a particular material system may behave differently as particle size, morphology, composition, and distribution of the hardening phase varies. The purpose of this thesis was to understand the mechanical and microstructural effects of combining titanium carbide with 431 series stainless steel to create a unique...