The diffusivity of water, fucose, proline, lysine, glutamic acid, glucose and sucrose was determined in a variety of inflammatory human synovial fluids. In view of the constituents of pathological synovial fluids one would predict impedence to solute movement. In several fluid diffusivity was enhanced relative to translational diffusion in water. In most fluids diffusivity was enhanced relative...

A physical model is described for the simultaneous enzymatic bioconversion of a nonelectrolyte solute and the passive transport of both the solute and product of the enzymatic reaction out of cells in culture suspension. The plasma membrane is assumed to be the rate-determining transport barrier. This model provides the basis for the experimental design and analysis of the Michaelis-Menten kine...

-The structure of fingers in a heat-solute system is investigated in the laboratory. In particular, the velocity of the fluid in the fingers and the horizontal and vertical length scales of the fingers, which form at the interface between two layers with the upper layer having an excess of the heat and solute but still less dense than the lower layer, are measured and related to the temperature...

In this work, we report the thermodynamic and ultrasonic properties of ascorbic acid (vitamin C) in water and in presence of newly synthesized ammonium based protic ionic liquid (diethylethanolammonium propionate) as a function of concentration and temperature. Apparent molar volume and apparent molar isentropic compression, which characterize the solvation state of ascorbic acid (AA) in presen...

A numerical model that includes the effects of mass transfer between mobile and immobile liquid phases, advection, hydrodynamic dispersion, and melt-freeze episodes was developed to simulate ionic solute transport in melting snow. Model calibration using a tracer-infused laboratory snowpack experiment yielded a dispersivity of 0.05 cm and a mobile-immobile phase mass-transfer coefficient of 4 3...

Single and ternary solute gas phase adsorption isotherms were conducted in this study to evaluate the effectiveness of a simple constant volume method, which was utilized by using Tedlar gas sampling bags as a constant volume batch reactor. For this purpose, gas phase adsorption of toluene, methyl ethyl ketone (MEK), and methyl isobutyl ketone (MIBK) on two types of activated carbons, BPL-bitum...

We examined the accumulation of organic solutes under optimum growth conditions in 12 species of thermophilic and hyperthermophilic Archaea belonging to the Crenarchaeota and Euryarchaeota. Pyrobaculum aerophilum, Thermoproteus tenax, Thermoplasma acidophilum, and members of the order Sulfolobales accumulated trehalose. Pyrococcus furiosus accumulated di-myo-inositol-1,1(prm1)(3,3(prm1))-phosph...

This paper presents an experimental and computational investigation of coupled consolidation and contaminant transport in compressible porous media. Numerical simulations were performed using the CST2 computational model in which a dual-Lagrangian framework is used to separately follow the motions of fluid and solid phases during consolidation. Diffusion and large strain consolidation tests wer...

Cloud water samples were taken in September/October 2010 at Mt. Schmücke in a rural, forested area in Germany during the Lagrange-type Hill Cap Cloud Thuringia 2010 (HCCT-2010) cloud experiment. Besides bulk collectors, a three-stage and a five-stage collector were applied and samples were analysed for inorganic ions (SO 4 ,NO − 3 , NH + 4 , Cl , Na, Mg, Ca, K), H2O2 (aq), S(IV), and dissolved ...

Reverse osmosis (RO) is a compact process that has potential for the removal of ionic and organic pollutants for recycling space mission wastewater. Seven candidate RO membranes were compared using a batch stirred cell to determine the membrane flux and the solute rejection for synthetic space mission wastewaters. Even though the urea molecule is larger than ions such as Na+, Cl-, and NH4+, the...