In the present work, Iranian natural zeolite particles (NZ) as an abundant and low-cost resource were modified by chemical covalent attachments of commercially available stearic acid (SA) with tunable hydrophobic/hydrophilic properties. The versatile, simple, and green technique of mechanogriding was performed for the hydrophobic derivatisation of NZ. The NZ and as-prepared modified particles w...

Freshly prepared ZnO nanoparticles were used as an effective heterogeneous base catalyst for the synthesis of aryloximes. The conversion of arylaldehydes and arylketones into the corresponding oximes (up to quantitative yields) was achieved by simply mixing the liquid reactants and hydroxylamine hydrochloride with ZnO nanoparticles under solvent-free condition. The procedure was carried out und...

The thermal [4+2] cycloadditions of 3-acetyl-, 3-carbamoyl, and 3-ethoxycarbonylcoumarins with 2,3-dimethyl-1,3-butadiene under solvent free conditions are reported, as well as the epoxidation reactions of some adducts. Discussion is focused on the structural features of the Diels-Alder adducts and their epoxides, based upon NMR, X-ray, and mass spectral data, and supported by ab initio theoret...

Click chemistry provides extremely selective and orthogonal reactions that proceed with high efficiency and under a variety of mild conditions, the most common example being the copper(I)-catalysed reaction of azides with alkynes1,2. While the versatility of click reactions has been broadly exploited3–5, a major limitation is the intrinsic toxicity of the synthetic schemes and the inability to ...

There is large and growing interest in making a wide variety of materials and surfaces antimicrobial. Initiated chemical vapor deposition (iCVD), a solventless lowtemperature process, is used to form thin films of polymers on fragile substrates. To improve research efficiency, a new combinatorial iCVD system was fabricated and used to efficiently determine the deposition kinetics for two new po...