Spiral k-space magnetic resonance spectroscopic imaging (MRSI) requires high performance from gradient hardware systems. During the readout phase, oscillating gradients are continuously played out, which can cause undesired effects. These effects on the quality of SI data are non-intuitive because of their time-varying nature. In this work we describe the effects of undesirable gradient perform...

Metal ion analysis is an important aspect during water quality monitoring of either surface or ground water sources. In spite of the availability of several other metal ion analysis techniques for drinking water samples, today atomic absorption spectroscopic (AAS) method is most commonly being used due to the reproducibility of results, short analysis time, cost effective, lower level detection...

We report the first spectroscopic detection of a kink MHD oscillation of a solar coronal structure by the Extreme-Ultraviolet Imaging Spectrometer (EIS) on the Japanese Hinode satellite. The detected oscillation has an amplitude of 1 km s−1 in the Doppler shift of the FeXII 195 Å spectral line (1.3 MK), and a period of 296 s. The unique combination of EIS’s spectroscopic and imaging abilities e...

Beach rock has only rarely been observed in the coasts. It is a hard costal sedimentary formations consisting of various beach sediments, lithified through the precipitation of carbonate cements. One such formation is noted on the South East Coast of Tamilnadu, India. The objective of this contribution is to collect and review information on reported occurrences, characteristics and formation m...

Many diffusion-ordered spectroscopy (DOSY) NMR techniques have recently been developed to aid in the deconvolution of complex mixtures. Spectroscopic separation based on chemical and physical properties facilitates the identification of mixture components while eliminating time-consuming separation steps and preserving the chemical environment. One way to improve resolution in such experiments ...

Multivariate calibration is an important tool for spectroscopic measurement of analyte concentrations. We present a detailed study of a hybrid multivariate calibration technique, constrained regularization (CR), and demonstrate its utility in noninvasive glucose sensing using Raman spectroscopy. Similar to partial least squares (PLS) and principal component regression (PCR), CR builds an implic...

With the goal of confirming the metallicity “excess” observed in stars with planetary mass companions, we have conducted a high-precision spectroscopic study of a “comparison” sample of dwarfs included in the CORALIE extra-solar planet survey (Santos, Israelian, & Mayor 2001). The targets were chosen following two basic criteria: they make part of a limited volume and they do not present the si...

A novel in situ IR spectroscopic approach is demonstrated for the characterization of hydrogenase during catalytic turnover. E. coli hydrogenase 1 (Hyd-1) is adsorbed on a high surface-area carbon electrode and subjected to the same electrochemical control and efficient supply of substrate as in protein film electrochemistry during spectral acquisition. The spectra reveal that the active site s...

Supernova rates are directly coupled to high mass stellar birth and evolution. As such, they are one of the few direct measures of the history of cosmic stellar evolution. In this paper we describe an probabilistic technique for identifying supernovae within spectroscopic samples of galaxies. We present a study of 52 type Ia supernovae ranging in age from -14 days to +40 days extracted from a p...

Synopsis The STM provides real space atomic resolution images through tunneling current between a conductive tip and a conductive/semiconductive surface. In this lab unit, we employ two STM modes, i.e., constant current imaging mode and tunneling spectroscopy mode, to study HOPG (graphite) and gold (Au). HOPG is one of well studied materials and serves as a standard for STM technique, and the i...