This paper describes a new multilayer TBC that incorporates a 10 μm-thick oxygen barrier layer of yttrium–aluminum garnet (YAG) into a typical YSZ TBC system. The thermal conductivity of as-sprayed YAG/YSZ coatings was reduced due to excessive porosity and amorphous areas in the YAG layer. After long-term heat treatments, the conductivity of the multilayer was unaffected by the presence of YAG....

Thermal barrier coating (TBC) systems are susceptible to delamination failures in the presence of a large thermal gradient. These failures, which occur within the TBC layer, are very different in character from those associated with the thermally grown oxide. Three possible causes of internal delamination are analyzed. In all cases, the thermomechanical properties of the TBC are allowed to vary...