TiO2 nanoparticle-encapsulating poly(vinyl chloride) (TEPVC) was combusted in a well-controlled laboratoryscale incinerator at a temperature of 700 °C, and then dioxins (PCDDs, PCDFs and coplanar-PCBs) formed in the exhaust gases were analyzed by high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS). TEPVC sample was prepared by the suspension polymerization of vinyl ...

It is known that water purified by conventional TiO2 photocatalysts may not be safe enough for drinking, due to the toxicity by tiny existence of TiO2 nanoparticles after water treatment. We herein demonstrate a facile design of a three-dimensional (3D) TiO2 photocatalyst structure with which both the efficiency of purification and the safety level of the final purified water can be improved an...

ag/tio2 photocatalytic nanoparticles by two methods, the sol – gel using a reducing agent and spattering was produced. crystalline phase of titanium dioxide was investigated in both. ag/tio2 peak in the sol – gel method at temperatures of 300,500 and 6000c were studied. ag/tio2 peak at different temperatures were determined using the spattering. xrd patterns of calcined this is tio2 and ag/ tio2.

Semiconductor photocatalysis has been intensively studied in recent decades for a wide variety of application such as hydrogen production from water splitting and water and air treatment. The majority of photocatalysts are, however, wide band-gap semiconductors which are active only under UV irradiation. In order to effectively utilize visible solar radiation, this thesis investigates various t...

The metallorganic chemical vapor deposition method was successfully used to synthesize pure TiO2 and Nd3 -, Pd2 -, Pt4 -, and Fe3 -doped TiO2 nanoparticles. Polycrystalline TiO2 structure was verified with x-ray diffraction, which showed typical characteristic anatase reflections without any separate dopant-related peaks. Transmission electron microscopy observations confirmed the existence of ...

tio2 nanoparticles, as a photocatalyst for oxidation of dimethyl methylphosphonate (dmmp) as an organophosphorus simulant of chemical warfare agent, were prepared by using sol-gel method. the prepared nanoparticles were then modified with transition metals in order to decrease the electron-hole recombination and increase the photocatalytic activity. transition metal ions including pt, pd and ni...

Electrodeposition is a simple and economic technique for precision coating of different shaped substrates with pure metal, alloy or composite films. Dc electrodeposition was used to produce Cr, Co-Cr and Co-Cr/TiO2 nano-composite coatings from Cr(III) based electrolytes onto 316L SS substrates. The effects of TiO2 nanoparticles concentration on co-deposition of these particles along with Cr con...

Nanoparticles (NPs) of zinc oxide (ZnO) and titanium dioxide (TiO2) are receiving increasing attention due to their widespread applications. The aim of this study was to evaluate the toxic effect of ZnO and TiO2 NPs at different concentrations (50, 100, 250 and 500 ppm) and compare them with their respective salts using a battery of cytotoxicity, and genotoxicity parameters. To evaluate cytotox...

objective(s): first-principles calculations have been carried out to investigate the interaction of aspirin molecule with nitrogen-doped tio2 anatase nanoparticles using the density functional theory method in order to fully exploit the biosensing capabilities of tio2 particles. methods: for this purpose, we have mainly studied the adsorption of the aspirin molecule on the fivefold coordinated ...

the degradation of poly (vinyl pyrrolidone) (pvp) by means of ultrasound irradiation and itscombination with heterogenous photocatalysis (tio2 nanoparticles) was investigated. emphasiswas given on the effect of additive on degradation rate constants. 24 khz of ultrasoundirradiation was provided by a sonicator, while an ultraviolet source of 30 w was used for uvirradiation. to increase the effic...