We explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized TiO2 matrix. These electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to TiO2 nanotubes, respectively. Titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (EG) fluoride-c...

Nitrogen oxides (NOx) released in atmosphere by fuels combustion lead to photochemical smog and acidic rains and have negative effects on human`s nervous system. In this research nanocomposite membranes of Poly Vinylidene Fluoride (PVDF)/ Poly Dimethylsiloxane (PDMS) and Titanium Dioxide nanoparticles (TiO2) with different weight percentage of TiO2 (0.5 and 1) for adsorption of NOx were prepare...

Glycosynthases are synthetic enzymes derived from retaining glycosidases in which the catalytic nucleophile has been replaced. The mutation allows irreversible glycosylation of sugar acceptors using glycosyl fluoride donors to afford oligosaccharides without any enzymatic hydrolysis. Glycosynthase technology has proven fruitful for the facile synthesis of useful oligosaccharides, therefore the ...

This study describes the synthesis of a fluoroethylated derivative of [N-methyl-C]2-(40-methylaminophenyl)-6hydroxybenzothiazole ([C]6-OH-BTA-1; Pittsburgh Compound B (PIB)), an already established amyloid imaging agent. The [C]methylamino group of [C]6-OH-BTA-1 was formally replaced by a fluoroethyl group in a cold synthesis via N-alkylation of N-Boc-2-(40-aminophenyl)-6-(methoxyethoxymethoxy)...

Fermented culture of Streptomyces fulvissimus was found to secrete an antibacterial protein inhibitory to Micrococcus luteus, Bacillus subtilis, Bacillus cereus and methicillin resistant Staphylococcus aureus (MRSA) strains. The extracellular protein from the fermented culture on concentration revealed a high molecular weight peptide of 63kDa on SDS-PAGE gel and the region on gel displayed inhi...

Titanium(IV) complexes exhibit high potential as anti-tumor agents, particularly due to their low intrinsic toxicity and cytotoxicity toward cisplatin resistant cells. Nevertheless, Ti(IV) complexes generally undergo rapid hydrolysis that previously hampered their utilization as anticancer drugs. We recently overcame this difficulty by developing a highly stable Ti(IV) complex that is based on ...

Mold powders are fluxing agents used as raw materials in the steel industry, which play very important role in processing stability and final surface quality of a product. Surface quality depends particularly on the viscosity and the heat transfer of infiltrated mold flux between the mold wall and the solidified steel shell. Heat flux across the interfacial gap depends on thermal properties of ...

Single crystals of NbF4, niobium(IV) tetra-fluoride, were synthesized by disproportionation of Nb2F5 at 1273 K in a sealed niobium tube, extracted and studied by single-crystal X-ray diffraction. Previous reports on the crystal structure of NbF4 were based on X-ray powder diffraction data and the observed isotypicity to SnF4 [Gortsema & Didchenko (1965 ▸). Inorg. Chem. 4, 182-186; Schäfer et al...

The biochemical properties of a purified enzyme of a new alkalophillic endo-1,4-beta-xylanase gene, KRICT PX2 (GU967374), which was isolated from Paenibacillus sp. HPL-002 (KCTC11410BP) and expressed in E. coli, were investigated. The specific activity of the purified xylanase was 51.26 μmol/min/mg proteins. The Km and Vmax values of the protein for birch wood xylan were also verified to have 0...