We determine enhancement ratios for NOx, PAN, and other NOy species from boreal biomass burning using aircraft data obtained during the ARCTAS-B campaign and examine the impact of these emissions on tropospheric ozone in the Arctic. We find an initial emission factor for NOx of 1.06 g NO per kg dry matter (DM) burned, much lower than previous observations of boreal plumes, and also one third th...

Tropospheric ozone (O 3 ) negatively impacts human health and is also a greenhouse gas.

[1] Observations have revealed widespread emissions of alkyl nitrates from the tropical and Southern Oceans. We present the first chemical transport model simulations to examine the global impact of these emissions. Matching observed atmospheric abundances, we derive a total oceanic flux of methyl nitrate (MeONO2) and ethyl nitrate (EtONO2) equivalent to 0.35 Tg of N per year, which contributes...

The impact of the East Asian monsoon (EAM) on climatology and interannual variability of tropospheric ozone (O3) over the coastal South China was investigated by analyzing 11 years of ozonesonde data over Hong Kong with the aid of Lagrangian dispersion modeling of carbon monoxide and calculation of an EAM index. It was found that the seasonal cycle of O3 in the lower troposphere is highly relat...

[1] We interpret the distribution of tropical tropospheric ozone columns (TTOCs) from the Total Ozone Mapping Spectrometer (TOMS) by using a global three-dimensional model of tropospheric chemistry (GEOS-CHEM) and additional information from in situ observations. The GEOS-CHEM TTOCs capture 44% of the variance of monthly mean TOMS TTOCs from the convective cloud differential method (CCD) with n...

[Comment]: However, the authors have not considered the prominent way aerosols impact tropospheric ozone formation via heterogeneous reactions which leads me to question the conclusions of this study. Several studies have highlighted the role of aerosols in modulating ozone via heterogeneous reactions (eg., Liao and Seinfeld, 2005; Ti et al., 2005; Pozzoli et al., 2008; Xu et al., 2012; Lou et ...

Measurement of ozone in the urban environment of Hyderabad was carried out synoptically at four different locations during the year 2011. The amount of ozone in the ambient air varied from 20 μg/m3 to 273 μg/m3 exhibiting wide temporal and seasonal variation. The ozone concentration is invariably peak at noon time and remained high during early summer and spring period. On many occasions 1-h oz...

We examine the distribution of tropical tropospheric ozone (O3) from the Microwave Limb Sounder (MLS) and the Tropospheric Emission Spectrometer (TES) by using a global three-dimensional model of tropospheric chemistry (GEOS-Chem). MLS and TES observations of tropospheric O3 during 2005 to 2009 reveal a distinct, persistent O3 maximum, both in mixing ratio and tropospheric column, in May over t...

We present, to the best of our knowledge, a new method to retrieve tropospheric ozone (O3) profiles from ground-based ultraviolet spectroscopic measurements. This method utilizes radiance spectra in the Huggins bands (i.e., 300-340 nm) measured at three off-axis angles (e.g., 45 degrees, 75 degrees, and 85 degrees) normalized to direct-Sun irradiances or zenith-sky radiances with the total colu...