In recent years, several new methods for the identiica-tion of approximate models of an open loop plant on the basis of closed loop data have been presented. In this paper, we extend such a method to the nonlinear case: we consider that both the plant and the controller can be nonlinear. The method that is considered is a two-step procedure, i.e. the sensitivity function of the closed loop syst...

We present sufficient convergence conditions for two-step Newton methods in order to approximate a locally unique solution of a nonlinear equation in a Banach space setting. The advantages of our approach under the same computational cost over other studies such as [9–25] for the semilocal convergence case are: weaker sufficient convergence conditions, more precise error bounds on the distances...

An important stage in macromolecular crystallography is that of phase extension and refinement when initial phase estimates are available from isomorphous replacement or anomalous scattering or other methods. For this purpose, an alternative method called the twin variables (TwiV) method has been proposed. The algorithm is based on alternately transferring the phase information between the twin...

The mechanism of melibiose symport by the melibiose permease of Escherichia coli was studied by looking at the modifications of the facilitated diffusion properties of the permease which arise upon substitution of the coupled cations (H+, Na+, or Li+). Kinetic analysis of melibiose influx and efflux down a concentration gradient, exchange at equilibrium, and counterflow were examined in de-ener...

Ab initio calculations at the G3 level were used in a theoretical description of the kinetics and mechanism of the chlorine abstraction reactions from mono-, di-, tri- and tetra-chloromethane by chlorine atoms. The calculated profiles of the potential energy surface of the reaction systems show that the mechanism of the studied reactions is complex and the Cl-abstraction proceeds via the format...

In this work, based on experimental observations and exact theoretical predictions, the kinetic scheme of RAFT polymerization is extended to a wider range of reactions such as irreversible intermediate radical terminations and reversible transfer reactions. The reactions which have been labeled as kinetic scheme are the more probable existing reactions as the theoretical point of view. The ...