نتایج جستجو برای: valence
تعداد نتایج: 17914 فیلتر نتایج به سال:
We report measurements of the valence band width in compressed Ge determined from x-ray emission spectra below the Ge K edge. The width of the valence band does not show any pressure dependence in the semiconducting diamond-type structure of Ge below 10 GPa. On the other hand, in the metallic beta-Sn phase above 10 GPa the valence band width increases under compression. Density-functional calcu...
Spatial models of voting have dominated mathematical political theory since the seminal work of Downs. The Downsian model assumes that each elector votes on the basis of his utility function which depends only on the distance between his preferred policy platform and the ones proposed by candidates. A succession of papers introduces valence issues into the model, i.e. candidates’ characteristic...
Here the correlation between the chemical shift in X-ray absorption spectroscopy, the geometrical structure and the formal valence state of the Mn atom in mixed-valence manganites are discussed. It is shown that this empirical correlation can be reliably used to determine the formal valence of Mn, using either X-ray absorption spectroscopy or resonant X-ray scattering techniques. The difficulti...
A new cobalt bis(semiquinone) valence tautomer is reported featuring a terthienyl substituent, which undergoes electropolymerization to produce a valence tautomeric conducting metallopolymer.
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