Weak interlayer interactions in van der Waals crystals facilitate their mechanical exfoliation to monolayer and few-layer two-dimensional materials, which often exhibit striking physical phenomena absent in their bulk form. Here we utilize mechanical exfoliation to produce a two-dimensional form of a mineral franckeite and show that the phase segregation of chemical species into discrete layers...

The force field used was MMF94s, without any solvent treatment. A constant dielectric of 1.0 was employed for the electrostatic treatment, whereas the charges were assigned by the force field (Fig. 1). Moreover, an extended non-bonded cut-off was set, for taking into account the best maximum distances over which hydrogen bonding, Van der Waals and electrostatic contributions to the molecular po...

We present a new approach to calculate the attractive long-range vortex-vortex interaction of the van der Waals type present in anisotropic and layered superconductors. The mapping of the statistical mechanics of two-dimensional charged bosons allows us to define a Casimir problem: Two half spaces of vortex matter separated by a gap of width R are mapped to two dielectric half planes of charged...

We utilize classical molecular dynamics to study the effects of intrinsic, interlayer friction between graphene monolayers, as well as extrinsic attachment or clamping strength between graphene and a model silicon substrate on the energy dissipation Q-factors of oscillating graphene nanoresonators. Both interlayer friction and attachment effects are found to significantly degrade the graphene Q...

The calculated electron density distribution for orpiment, As(2)S(3), reveals that As-S, S-S, and As-As bond paths are associated with the experimental interlayer directed bonded interactions detected in a combined infrared and Raman study. The successful modeling of the infrared- and Raman-determined interlayer bonded interactions together with bond paths and the structuralization of a variety...

Encouraged by recent advances in revealing significant effects of van der Waals wells on reaction dynamics, many people assume that van der Waals wells are inevitable in chemical reactions. Here we find that the weak long-range forces cause van der Waals saddles in the prototypical C(1D)+D2 complex-forming reaction that have very different dynamical effects from van der Waals wells at low colli...

An atomic force microscope (AFM) was used to measure the interactions between a flat Teflon AFTM surface and an -alumina or amorphous silica sphere in cyclohexane as a function of distance of separation. Repulsive van der Waals (vdW) forces were predicted for the interactions between Teflon AFTM and -alumina or amorphous silica according to the negative Hamaker constants, which were calculated ...

We study the van der Waals (vdW) interaction between a polarizable particle and grounded conducting corrugated surface. For sinusoidal corrugations, one knows that, under action of lateral vdW force, an isotropic is always attracted to nearest corrugation peak, with such behavior called in present paper as peak regime. Here, considering anisotropic particle, making analytical calculations valid...