Recently Garel, Monthus and Orland (Europhys. Lett. 55, 132 (2001)) considered a model of DNA denaturation in which excluded volume effects within each strand are neglected, while mutual avoidance is included. Using an approximate scheme they found a first order denaturation. We show that a first order transition for this model follows from exact results for the statistics of two mutually avoid...

The zero temperature Mott transition region in antiferromagnetic, spin S = 52 MnO is probed using the correlated band theory LSDA + U method. The first transition encountered is an insulator–insulator volume collapse within the rocksalt structure that is characterized by an unexpected Hund’s rule violating ‘spin-flip’ moment collapse. This spin-flip to S = 12 takes fullest advantage of the anis...

The equilibrium dissociation of recombinant human IFN-gamma was monitored as a function of pressure and sucrose concentration. The partial molar volume change for dissociation was -209 +/- 13 ml/mol of dimer. The specific molar surface area change for dissociation was 12.7 +/- 1.6 nm2/molecule of dimer. The first-order aggregation rate of recombinant human IFN-gamma in 0.45 M guanidine hydrochl...

We model two-dimensional systems of granular aggregates confined between two planes and demonstrate that at a critical grain volume fraction an abrupt rigidity transition occurs. This transition is observed both in static and shear tests. The grain volume fraction at which the transition occurs, νc, decreases with increasing friction between the grains. Densely packed grains, with a volume frac...

This paper experimentally investigates the rheology of dense granular flow through its solid-like to fluid-like transition. Between the well-established flow regimes – quasi-static and grain-inertial – the physical description of the transition remains elusive. Our experiment uses a top-rotating torsional shear cell capable of ±1 μm accuracy in height and 5 decades (10−3 − 100 rad s−1) in rotat...

An azobenzene-containing heteropolymer gel in an ionic liquid exhibits thermally reversible volume phase transition when the azobenzene moiety mainly exists in the cis-state, whereas the transition becomes irreversible when it is in the trans-state and an interlocked collapsed state is stabilized; however, the unlocking of the metastable state occurs by UV light irradiation.

We present the results of our large scale 4-dimensional (4d) lattice simulations for the MSSM electroweak phase transition (EWPT). We carried out infinite volume and continuum limit extrapolations and found a transition whose strength agrees well with perturbation theory. We determined the properties of the bubble wall that are important for a successful baryogenesis.

Potential functions allow the definition of both an implicit surface and its volume. In this representation, two categories can be distinguished: bounded and unbounded representations. Boolean composition operators are standard modelling tools allowing complex objects to be built by the combination of simple volume primitives. Though they are well defined for the second category, there is no cl...

We present evidence for Mott quantum criticality in an anisotropic two-dimensional system of coupled Hubbard chains at half-filling. In this scenario emerging from variational cluster approximation and cluster dynamical mean-field theory, the interchain hopping t_{⊥} acts as a control parameter driving the second-order critical end point T_{c} of the metal-insulator transition down to zero at t...

In this work, a series of transition metal (Cr, Mn, Fe, and Co) doped kaolinite nanoclays were investigated by density functional theory (DFT) calculations. The influence of metal doping on geometric structure and electronic structure of kaolinite was analyzed. The ferromagnetic (FM), antiferromagnetic (AFM), and nonmagnetic (NM) states of transition metal (TM) doped kaolinite structures were s...