The formation of single-phase solid solutions iron oxide and manganese with a spinel structure in MnxFe3 – xO4 system (x = 0; 0.3; 0.6; 0.8; 1.0; 1.2; 1.4; 1.8) has been established by methods X-ray phase analysis infrared spectroscopy. maximum saturation magnetization was found for the composition Mn0.3 Fe2.7O4 (Ms 68 A ⋅ m2 kg−1 at 300 K Ms 85 5 K), which is associated change cationic distrib...