We show the design and synthesis of new perfluorinated nitrosopyrazolone-based ligands and the original method employed for their complexation of erbium ions in the presence of the co-ligand perfluorotriphenylphosphine oxide; the resulting chelate is non-hygroscopic, solution processable and possesses a NIR emission with lifetimes as long as 16 micros.

In the present work, four polymeric nanocomposite PNC coatings were prepared with different concentrations of yttrium aluminum garnet nanoparticles YAG-NPs in polyvinyl butyral PVB matrix. The corrosion protection of the PNC coatings applied on the carbon steel surface was investigated in 1.0 M HCl solution by electrochemical impedance spectroscopy EIS. The YAG-NPs were synthesized by pulse ele...

PURPOSE This in vitro study compared the effect of five different techniques on the surface roughness of feldspathic porcelain. MATERIALS AND METHODS 100 feldspathic porcelain disk samples mounted in acrylic resin blocks were divided into five groups (n=20) according to type of surface treatment: I, hydrofluoric acid (HFA); II, Deglazed surface porcelain treated with Neodymium:yttrium- alumin...

Single-crystal (SC) fibers have the potential of delivering extremely high laser energies. Sapphire fibers have been the most commonly studied SC fiber and the losses for sapphire fibers have been as low as 0.4 dB/m for a 300micron core-only fiber at 3 microns. In this study we report on the growth of SC yttrium aluminum garnet, Y3Al5O12 (YAG) fibers from undoped SC source rods using the Laser ...

The ultimate goal of the periodontal treatments is a regeneration of periodontium. Recently, laser irradiations are commonly used to improve wound repair. Because of many controversies about the effects of laser on soft tissue regeneration, more in vitro studies are still needed. The aim of the present in vitro study was to compare the effects of different doses of Er:YAG (erbium-doped:yttrium,...

Yttrium aluminum garnet (YAG) ceramics doped with Ce3+ was prepared by dry compaction using the common uniaxial pressing under powerful ultrasound assistance (PUA). The structure and luminescent properties of sintered were investigated. It demonstrated that ultrasonic assistant during has a positive effect on structural characteristics YAG: ceramics. material consolidation is very intensive acc...

A comparative study of thermal lensing effect in diode laser pumped Ng- and Np-cut Nd:KGd(WO4)2 (KGW) laser crystals was performed for laser emission polarized along the principle refractive axis, Nm. The thermal lens in the Ng-cut Nd: KGW was found to be weakly astigmatic with a positive refractive power for both the Nm- and Np-directions. For Np -cut Nd:KGW, strong astigmatism was observed an...

Prediction of the extent and time course of drug-drug interactions (DDIs) between the mechanism-based inhibitor diltiazem (DTZ) and the CYP3A4 substrate midazolam (MDZ) is confounded by time- and concentration-dependent clearance of the inhibitor. Semiphysiologically based pharmacokinetic (PBPK) models were developed for DTZ and MDZ with the major metabolite of DTZ, N-desmethyldiltiazem (nd-DTZ...

Er3+-doped fluorozirconate (ZrF4-BaF2-YF3-AlF3) and oxyfluoroaluminate glasses are successfully prepared here. These glasses exhibit significant superiority compared with traditional fluorozirconate glass (ZrF4-BaF2-LaF3-AlF3-NaF) because of their higher temperature of glass transition and better resistance to water corrosion. Judd-Ofelt (J-O) intensity parameters are evaluated and used to comp...

A new laser heating system has been set up to minimize the sample temperature gradients both radially and axially in a diamond anvil cell. A multimode Nd:YAG laser with a relatively flat top of intensity profile allows us to reduce the radial temperature gradient; the axial temperature gradient is minimized by heating samples at both sides. Three dimensional uniform temperatures of 1200 4000 K ...