Zirconium oxide and tantalum oxide films were deposited in an inverted cylindrical magnetron cathode using high power pulsed sputtering. Average power densities were between 5 and 7 W/cm2 and peak power densities were in the range of 0.5 kW/cm2. In all of the experiments the oxygen was introduced using flow control, and the current and voltage waveforms of the HPPMS supply changed in a reproduc...

PURPOSE The purpose of this study was to assess the surface characteristics and the biocompatibility of zirconium (Zr) coating on Ti-6Al-4V alloy surface by radio frequency (RF) magnetron sputtering method. MATERIALS AND METHODS The zirconium films were developed on Ti-6Al-4V discs using RF magnetron sputtering method. Surface profile, surface composition, surface roughness and surface energy...

PURPOSE This paper is focused on the works concerning preparation of zirconium oxide ceramic blocks recommended for CAD/CAM systems used in prosthetic dentistry for manufacturing fixed prosthetic restorations. METHODS Zirconium-yttrium-magnesium mixed ceramic oxides were prepared by sol-gel method via hydrolysis and condensation of zirconium alkoxide precursor (zirconium (IV) propoxide) with ...

BACKGROUND An increasing demand for esthetic restorations has resulted in an increased use of all-ceramic restorations, such as zirconium. However, one of the challenges the orthodontist must be willing to face is how to increase bond strength between the brackets and various ceramic restorations.Bond strength can beaffected bybracket type, by the material that bracketsaremade of, and their bas...

We investigate the potential for hydrogen storage of a new class of nanomaterials, metal-diboride nanotubes. These materials have the merits of a high density of binding sites on the tubular surfaces without the adverse effects of metal clustering. Using the TiB2 (8,0) and (5,5) nanotubes as prototype examples, we show through first-principles calculations that each Ti atom can host two intact ...

DENSE PERIODICAL PATTERNS IN PHOTONIC DEVICES:TECHNOLOGY FOR FABRICATION AND DEVICE PERFORMANCEbySABARISH CHANDRAMOHANDecember 2016 Advisor: Dr. Ivan AvrutskyMajor: Electrical EngineeringDegree: Doctor of Philosophy For the fabrication, focused ion beam parameters are investigated to successfullyfabricate dense periodical patterns, such as gratings, on hard transitio...

Four aluminas were used as supports for impregnation with a zirconium oxide with the aim to achieve a coating, without phase separation, between support and modifier. The supports were impregnated with different concentrations of zirconium aqueous resin, obtained through the polymeric precursor method. After impregnation the samples were calcined and then characterized by XRD, which led to iden...

G . H evesy has written that [6] 1 " In view of the I.great similarity b etween hafnium and zirconium, i t ris hardly possible to separate these two elements in a lsingle operation ." A simple one-step separation c adequ a te for analytical work has still to be developed for hafnium-ziTconium mixtures, although recent work employing ion exchange has developed suitable methods for the separation...

Titanium diboride (TiB2) is a low-density refractory material belonging to the family of ultra-high temperature ceramics (UHTCs). This paper reports on the production and microstructural and optical characterization of nearly fully dense TiB2, with particular interest to its potential utilization as novel thermal solar absorber. Monolithic bulk samples are produced starting from elemental react...