Metal-organic frameworks (MOFs) have recently received much attention as promising candidates for gas storage, chemical separation, and heterogeneous catalysis. However, the applicability of MOFs remains limited due to their relatively large band gaps. Here, on the basis of first-principles theory study, it is demonstrated that this problem could be overcome by tailoring Zn2+ ions in MOFs with ...

A new heterocyclic Schiff base ligand bis(2-(pyridin-2-ylimino)phenyl)-4,4'-(diazene-1,2diyl)dibenzoate (BPPD, L) and its metal complexes with divalent transition metal ions viz., Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized and characterized through IR, NMR and elemental analysis. The ligand and its complexes have been screened for the antibacterial activities towards bacteria Staph...

Cr, Co, Cu, Zn, Cd and Pb in the bottom sediments from 93 sites at Quiberon bay were analyzed by Inductively Coupled Plasma Mass Spectrometry (ICPMS) after acid extraction. The ranges of the concentration in the sediments are as follows: 27.3 μg/g (Cr), 11.6 μg/g (Co), 13.8 μg/g (Cu), 42.0 μg/g (Zn), 0.08 μg/g (Cd) and 17.8 μg/g (Pb). Potential contamination of the bay was assessed by Igeo and ...

The composition and stability of the complexes of isatin-β-thiosemicarbazone with Co(II), Ni(II), Cu(II), Zn(II), Pd(II) and Hg(II) have been investigated using spectrophotometric method at 30 °C and constant ionic strength of 0.1 mol dm-3 (KNO3) in 70 % ethanol. Experimental results indicate the formation of MeL and MeL2 complexes for Ni(II) and Co(II), and MeL for Cu(II), Zn(II), Pd(II) and H...

Twenty-six metals and the oxidative status in 71 patients affected by Parkinson's disease and 44 healthy individuals were compared in order to identify potential biomarkers of the disease. In the patients, the following significant imbalances were found (p < or = 0.05): i) in serum, an increment of Ca, Mg, Ni, Si and V, and a decrement of Cd, Co, Fe, Li, Sn, Zn and Zr; ii) in blood, raised leve...

The biogeochemical cycle of trace metals plays an important role in the coastal zone. distribution, interaction, and behavior dissolved surface bottom seawater are still unclear. This study analyzed distribution performed ecological health risk assessment (Zn, Cd, Co, Pb Cr) summer (August) 2019 2020 Yantai offshore area, China. Zinc (Zn), cadmium (Cd), cobalt (Co), lead (Pb) chromium (Cr) rang...

Magnetic transport properties in Ti(1-x)Co(x)O(2) and Zn(1-x)Co(x)O magnetic semiconductors have been studied experimentally and theoretically. A linear relation of lnρ versus T(-1/2) (ρ is sheet resistance and T is temperature), which shows different slopes and intersections at different magnetic fields, was observed experimentally in the low temperature range. The spin-dependent variable rang...

In this work we investigate the mechanism of Zn oxidation with CO2 and/or H2O to produce solar derived fuels (CO and/or H2) as part of the Zn/ZnO thermochemical redox cycle. It has been observed that the ZnO contamination of Zn produced by solar thermal reduction of ZnO (solar Zn) facilitates oxidation of the metallic Zn by CO2 and H2O, allowing for nearly complete conversion at temperatures as...

concentrations of eight metals namely, cr, mn, fe, co, ni, cu, zn and pb were examined in the surface sediments of discharge channels of six industries in lagos using x-ray fluorescence spectrometry.these channels drain into the isolo canal which empties into the lagos lagoon and eventually into the atlantic ocean. this study was conducted to detect any contamination levels within the sediments...