Two polyanions [SeI V2 PdII4 WVI14 O56 H]11- and [SeI V4 PdII4 WVI28 O108 H12 ]12- are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-...

The binuclear title complex, di-μ-iodido-bis(-{2-[(benzylamino-κN)meth-yl]phenyl-κC1}palladium(II)), [Pd2I2(C14H14N)2], was prepared by reaction of [Pd{C6H4(CH2NHCH2Ph)-2}(μ-OAc)]2 with NaI. It crystallizes with one discrete mol-ecule in the asymmetric unit. The mol-ecule presents an iodide-bridged dimeric structure with a cisoid arrangement with respect to the C,N-cyclo-palladated ligands. Bot...

[PdI2(μ-PPh2)(μ2-OAc)(PPh3)2] is the reduction product of PdII(OAc)2(PPh3)2, generated by reaction ‘Pd(OAc)2’ with two equivalents PPh3. Here, we report that PPh3 results in a nuanced disproportionation reaction, forming [Pd0(PPh3)3] and phosphinito-bridged PdI-dinuclear complex, namely [PdI2(μ-PPh2){κ2-P,O-μ-P(O)Ph2}(κ-PPh3)2]. The latter complex proposed to form abstraction an oxygen atom fro...

The use of weak bases and mild conditions is currently the most sustainable attractive synthetic approach for preparation late-transition metal complexes, some which are widely used in catalysis, medicinal chemistry materials science. Herein, cuprate, aurate or palladate species a continuous flow CuI, AuI PdII-NHC complexes reported. All reactions examined proceed under extremely make technical...

The title compound, hexa-kis-[μ3-1,2-bis-(tri-fluoro-meth-yl)ethene-1,2-di-thiol-ato]-octa-hedro-hexa-palladium(II), [Pd(C4F6S2)]6, crystallizes as its benzene solvate, [Pd(tfd)]6·2.5C6H6, where tfd is the di-thiol-ene S2C2(CF3)2. The mol-ecular structure of [Pd(tfd)]6 is of the hexa-metallic cube type seen previously in three examples of hexa-meric homoleptic palladium monodi-thiol-ene structu...