Two new spirostane glycosides, named polygokingiaside A (1) and B (2), 6 known (25 R)-26- O-( β-d-glucopyranosyl)-furost-5-en-3 β,22 α,26-triol 3- O-β-d-glucopyranosyl-(1→4)- β-d-galactopyranoside (3), S)-26- O-β-d-glucopyranosyl-(1→2)- β-d-glucopyranosyl-(1→4)- (4), (5), (23 S,25 R)-spirostan-5-en-3 β,23-dihydroxy-12-one-3- (6), (24 β,24-dihydroxy-12-one-3- (7), β-hydroxy-12-one-3- (8), were i...

The chemical composition of plant polyphenols Plantago major L. and lanceolata growing in Uzbekistan was studied. More than 20 compounds, including 7 flavonoids, 9 phenolic acids, 8 hydrolysable tannins, the ages which have been determined using physicochemical methods research isolated from plants. From P. L., along with well-known such as gallic acid, rutin, luteolin, isorhamnetin, hyperoside...

Background and objectives: Plumeria rubra L. (Apocynaceae) is a deciduous shrub or small tree cultivated in subtropical and tropical countries.  Its bark is prescribed to treat amoebic dysentery,   dropsy, jaundice, scabies, gonorrhea, venereal affections and wounds. In the present research, we aimed to isolate and identify the chemical constituents of the bark of ...

In 2- und 5-Position einer Phenylenbrücke eines schwach koppelnden gemischtvalenten [{Cp*(dppe)RuC≡C}2(μ-1,3-C6H4)]+ Komplexes hat ein OMe-Substituent nur geringen Einfluss auf dessen Elektronenstruktur. 4-Position hingegen erhöht dieser die elektronische Delokalisation im Grundzustand sowie Intensität des IVCT-Überganges. Schwingungsfrequenzen TDDFT-Berechnungen (LH20t-D3(BJ), def2-SVP, COSMO ...