The aggregation of two imidazolium-based ionic liquids, 1-ethly-3-methylimidazolium chloride (EMI(+)Cl(-)) and EMI(+) bis-(trifluoromethanesulfonyl)amide (EMI(+)TFSA(-)), in molecular liquids, water, methanol, acetonitrile, and benzene, has been studied by using the small-angle neutron scattering (SANS) technique. The SANS results have shown that the heterogeneity of EMI(+)Cl(-)-acetonitrile mi...

The complexation reaction between iodine and 1,10-Diaza-18-Crown-6 (DA18C6) has been studied in acetonitrile by spectrophotometric, biamperometric and conductometric techniques. The results are indicative of the formation of [(CH3CH)nI+.I¯3] from iodine and acetonitrile, and the formation of DA18C6 I+. I¯ from DA18C6 and [(CH...

acetonitrile used as a solvent in manufactures and affects to central nervous system from inhalation exposure. the aim of this study was to develop a micro-solid phase extraction method for  the determination of acetonitrile in the air matrix. the sampling was performed with a small diameter fused silica fiber coated with a thin film of stationary phase and was subsequently desorbed and analyze...

This paper presents simulation studies on the recovery of Acetonitrile from aqueous waste pharmaceutical processes. The focus is atmospheric distillation in two sequential columns to understand separation feasibility system; first column produces a distillate azeotropic composition, which mixed with fresh stream and fed second column, 99.9% pure residue. effect reflux ratio, reboiler duty flowr...

In the title compound, C8H6N2O3S, the dihedral angle between the nitro group and the benzene ring is 6.76 (9)°. The bond-angle sum at the S atom is 308.1°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds to generate (010) sheets. The crystal studied was found to be a racemic twin.

The retention behaviors of various low-molecular-weight compounds in low-temperature HPLC with an ODS (octadecyl silica) column and liquid CO2 mobile phase containing methanol or acetonitrile as modifiers were investigated. addition methanol/acetonitrile reduced the xanthone, which was dominated by content, independent modifier. Additionally, polycyclic aromatic hydrocarbons (PAHs) methanol/ace...