A series of Ag-Cu binary mixtures with different Ag/Cu ratios were supported on mordenite with different Si/Al ratios and were subsequently reduced under hydrogen in the temperature range 323K – 473K. Ag and Cu K-edge X-ray Absorption Spectroscopy (XAS) was conducted on these systems in-situ to monitor the reduction species formed and the kinetics of their reduction. In-situ XANES clearly demon...

Localized surface plasmon resonances (LSPRs) of degenerately doped copper chalcogenide nanoparticles (NPs) (Cu2-xSe berzelianite and Cu1.1S covellite) have been modified applying different methods. The comparison of the cation exchange (Cu2-xSe) and intercalation (Cu1.1S) of Ag(I) and Cu(I) has shown that Ag(I) causes a non reversible, air stable shift of the LSPR. This was compared to the infl...

in this paper, a novel method of producing bi-metallic alloy nanoparticles at low temperatures using hydrogen bombardment of thin films, deposited on glass substrates, is introduced. optical and morphological characteristics of the nanoparticles were extensively studied for various conditions of plasma treatment, such as plasma power density, temperature, duration of hydrogen bombardment, thick...

Peristaltic flow of hybrid nanofluid inside a duct having sinusoidally advancing boundaries and elliptic cross-section is mathematically investigated. The notable irreversibility effects are also examined in this mathematical research by considering descriptive entropy analysis. In addition, work provides comparison analysis for two distinct models: model (Cu-Ag/water) phase (Cu/water). A compr...

The wetting of thin Ag films on Cu 111 is characterized in detail with angle-resolved photoelectron spectroscopy. After constructing disordered Ag films on Cu 111 , we monitored the evolution of their layer-resolved Shockley states during wetting. Our results provide the first observation of a transitional state, which implies a coexistence of clean Cu 111 , 1 ML of Ag on Cu 111 , and 2 ML of A...

In the present study, the effect of exogenous silver nitrate (Ag+) and copper sulfate (Cu2+) applications on production of artemisinin and phenolic compounds as well as oxidative stress in the shoot cultures of Artemisia annua was investigated. A significant decrease in the shoot biomass and the total chlorophyll was observed in the shoots exposed to increased Ag concentration. Additionally, a ...

Resonant high-energy X-ray diffraction coupled to atomic pair distribution function analysis and computer simulations is used to study the atomic-scale structure of group 11 nanosized metals and binary alloy catalysts. We find that nanosized Cu is quite disordered structurally whereas nanosized Ag and especially Au exhibit a very good degree of crystallinity. We resolve Cu−Cu and Ag−Ag atomic c...

Ag2Cu3Cr2O8(OH)4, a new Ag-Cu-Cr-O layered mixed oxide, prepared by soft hydrothermal heterogeneous reactions, is reported. The new phase is an oxyhydroxide and presents a structure with alternating brucite-like Cu-O and Ag-O layers connected by individual chromate groups. The crystallographic structure has been solved and refined from high resolution powder X-ray diffraction data and is suppor...

We have studied the growth of Ag on bilayer high Co nanoislands on Cu(111) using scanning tunneling microscopy. Noble metal capping of magnetic nanostructures is known to influence the magnetism and knowledge of the growth is therefore important. We find that Ag preferentially nucleates on the Co nanoislands, initially leaving the free Cu sites clean. Furthermore we observe that those Co island...

This study represents the synthesis of dibenzo and dibenzodiaza crown ether precursors with various functional groups in good yield by employing four different methods using polar protic and aprotic solvents with high boiling points. Also the complexation abilities of all synthesized ligands with Cu , Zn , and Ag were studied by conductometry; thus the conductometric behavior of Cu(NO3)2, ZnCI2...