vo2+ and its complexes with ethylenediamine (en), acetylacetonate (acac), 2, 2’-bipyridine(bpy) ligands, immobilized within nanoreactors of al-mcm-41 designated as vo2+/al-mcm-41 or vol2/al-mcm-41, were prepared and characterized by x-ray powder diffraction (xrd), ft-ir, bet nitrogen adsorption-desorption and chemical analysis techniques. vo2+/al-mcm-41 and vol2/al-mcm-41 were found to catalyze...

The synthesis and characterization of new molecular sieves of the MCM-41 type are presented in this study. Samples were obtained from the alkoxides of Si, Ti and Al and different long-chain amine and alkylammonium salts surfactants, by the sol-gel method, through moderate agitation at room temperature. The reactions were conducted in two steps, acid hydrolysis (pH=2) and alkaline condensation (...

We report the development of a combined strategy for high capacity, comprehensive enrichment of endogenous peptide from complex biological samples at natural pH condition. MCM-41 nanoparticles with highly ordered nanoscale pores (i.e. 4.8nm) and high-surface area (i.e. 751m(2)/g) were synthesized and modified with strong cation-exchange (SCX-MCM-41) and strong anion-exchange (SAX-MCM-41) groups...

NiMo catalysts supported on mesoporous MCM-41 type materials shaped with binder were tested for activity in the hydrodesulfurization of 4,6-dimethyldibenzothiophene (4,6-DMDBT) and diesel fuel fraction (0.92 wt% sulfur). The aim investigation was to evaluate effect ion exchange protons Al- or Ti-substituted supports. subjected catalytic systems NiMo/HAlMCM-41 NiMo/HTiMCM-41, comparison purposes...

Tetraethylenepentamine (TEPA)-based mesoporous MCM-41 is used as the adsorbent to determine the CO2 desorption kinetics of amine-modified materials after adsorption. The experimental data of CO2 desorption as a function of time are derived by zero-length column at different temperatures (35, 50, and 70 ◦C) and analyzed by Avrami’s fractional-order kinetic model. A new method is used to distingu...

Binuclear redox sites consisting of a Zr oxo-bridged to a Cu(I) center have been obtained on the pore surface of MCM-41 silicate sieve by a stepwise grafting procedure, along with isolated metal centers. The bimetallic site features a Zr(IV)-O-Cu(I) to Zr(III)-O-Cu(II) metal-to-metal charge-transfer (MMCT) absorption extending from the UV region to about 500 nm. The Zr-O-Cu linkage is revealed ...