A 3x3x3 nm cubic coordination compound quantitatively self-assembled from 6 palladium ions and 12 bent ligands with a 90 degrees bend angle.

The far-infrared laser electric resonance spectra of the prototypical atom-diatom complex ArH3%Z1 are analyzed using improved zero-field molecular constants, yielding accurate permanent and transition dipole moments for the three lowest excited van der Waals vibrational states. The constants are obtained from a multistate fit to previous microwave, far-infrared laser electric resonance, and far...

Extending a molecular field model for the orientational order in the nematic phase, we calculate the (2)H-NMR splittings for the achiral solute 8CB-d2 in the twist-bend nematic phase formed by the achiral liquid crystal dimer CB7CB. We give an explanation for the enantiotopic discrimination observed in the spectra and comparison with experimental data allows us to provide quantitative estimates...

A state of matter in which molecules show a long-range orientational order and no positional order is called a nematic liquid crystal. The best known and most widely used (for example, in modern displays) is the uniaxial nematic, with the rod-like molecules aligned along a single axis, called the director. When the molecules are chiral, the director twists in space, drawing a right-angle helico...

Use the Spur dike as one of the easiest ways to protect the costal of the river has always been of interest to River engineers.The aim of this study was numerical investigate, the effect of distance and angle of the spur dikes parameters  on the pattern of distribution of average velocity  and the location of maximum velocity position at a mild 90 degree bend. For this purpose used ANSYS CFX so...

We present a study of the bend angle distribution of semiflexible polymers of short and intermediate lengths within the wormlike chain model. This enables us to calculate the elastic response of a stiff molecule to a bending moment. Our results go beyond the Hookean regime and explore the nonlinear elastic behavior of a single molecule. We present analytical formulas for the bend angle distribu...

One of the most sensitive features of sheet metal forming processes is the elastic recovery during unloading, called spring-back, which leads to some geometric changes in the product. This phenomenon will affect bend angle and bend curvature, and can be influenced by various factors. In this research, the effects of anisotropy i.e., the rolling direction of 0° , 45° & 90° of ultra low carbon st...

The survival curves for a population of reactivated spermatozoa exposed to digestion by trypsin indicate that a large number of trypsin-sensitive targets must be digested before the flagellum disintegrates. Changes in flagellar movement during trypsin digestion can be very small, especially when the spermatozoa are reactivated at 0.25 M KCl. They are not the changes which would be expected if e...

HU, an architectural DNA-binding protein, either stabilizes DNA in a bent conformation or induces a bend upon binding to give other proteins access to the DNA. In this study, HU binding affinity for a bent DNA sequence relative to a linear sequence was investigated using fluorescence anisotropy measurements. A static bend was achieved by the introduction of two phased A4T4 tracts in a 20 bp dup...

Pigging is a significant part of a pipeline system that is required for production and operational maintenance. However, if the bend is not set properly, it is likely to cause congestion, which could cause the pipeline system to deviate from its normal operation or even lead to cracks or explosions due to overloaded stress. Due to the potential risk mentioned above, this report aims to build an...