The purpose of this study was to develop the pathway of silk fibroin (SF) biopolymer surface induced cell membrane protein activation. Fibroblasts were used as an experimental model to evaluate the responses of cellular proteins induced by biopolymer material using a mass spectrometry-based profiling system. The surface was covered by multiwalled carbon nanotubes (CNTs) and SF to increase the s...

The aim of this work is to develop a preconcentration procedure of Cd(2+), Zn(2+) and Cu(2+) in environmental waters using olive pomace (OP) prior to their determination by flame atomic absorption spectrometry (FAAS). Raw OP as preconcentrating sorbent was found to have low permeability towards the passed water samples and thus long time was needed. Even reducing the vacuum pressure caused cart...

A new biosorbent was developed by coating chitosan, a naturally and abundantly available biopolymer, on to polyvinyl chloride (PVC) beads. The biosorbent was characterized by FTIR spectra, porosity and surface area analyses. Equilibrium and column flow adsorption characteristics of copper(II) and nickel(II) ions on the biosorbent were studied. The effect of pH, agitation time, concentration of ...

Integrated gasification combined cycle with CO 2 capture and sequestration (IGCC-CCS) emerges as one of the most promising technologies for reducing CO 2 emission from coal power plant without reducing thermal efficiency significantly. However the high capital cost of these plants has limited their deployment. The current solvent-based low-temperature CO 2 capture process (Selexol process) is e...

Interaction between electric charges is an important factor in protein adsorption. Similar charge signs on the protein and the sorbent surface opposes adsorption, but whether it prevents ad.: sorption depends on other factors such as dehydration of the protein and the sorbent and structural rearrangements in the protein molecule. Ribonuclease, that does not strongly change its structure upon ad...

AIMS The effect of synthetic media on the submerged mycelial growth and exo-biopolymer production in various edible mushrooms was investigated in shake flask culture. METHODS AND RESULTS Among 19 mushrooms examined, the relatively high yield in mycelial biomass and exo-biopolymer production was achieved in potato malt peptone (PMP) medium. In particular, Ganoderma lucidum NO. 1 and Phellinus ...

A magnetic sorbent with stable and superior magnetic behaviour was developed for His-tagged protein purification by immobilized metal affinity chromatography (IMAC). Magnetic, monodisperse and porous silica microspheres 6 mm in size, with bimodal pore size distribution including both mesoporous and macroporous compartments were synthesized as the base material by a staged-shape template hydroly...

Sorbent material based on a novel thiosemicarbazone compound, C H N S, was prepared by 12 18 4 immobilizing the ligand into gel matrix (SG). The SG sorbent was characterized by FT-IR, EDX, SEM, TEM and TGA. The competitive sorption characteristics of eight transition metal ions (Ag , Cu , Co , Ni , Fe , Pb , Zn + 2+ 2+ + 3+ 2+ 2+ and Mn ) using batch method was studied using atomic absorption s...

Future large-scale production of H2 for use as a clean fuel will likely depend upon gasifying coal or biomass followed by steam reforming the resulting gas mixture and separating the CO2 byproduct. The process of steam reforming and CO2 separation can be greatly simplified by utilizing a new material that combines a reforming catalyst with a sorbent for CO2. Such a material was prepared in the ...

Batch sorption experiments using a starch-based sorbent were carried out for the removal of heavy metals present in industrial water discharges. The influence of contact time, mass of sorbent and pollutant load was investigated. Pollutant removal was dependent on the mass of sorbent and contact time, but independent of the contaminant load. The process was uniform, rapid and efficient. Sorption...