The Wunugetushan large porphyry Cu–Mo deposit in NE China is hosted by Mesozoic quartz monzonite and has a Mo-rich core Cu-rich rim space. In this paper, melt inclusions intrusions fluid different-stage veins were studied to explore potential parameters leading decoupling. Melt have rhyolitic compositions of 71.7–85.3 wt.% SiO 2 , 1.9–31.3 ppm Cu 1.7–2.6 Mo. Hydrothermal activity occurred over ...

A potentially useful trianionic ligand for the reduction of dinitrogen catalytically by molybdenum complexes is one in which one of the arms in a [(RNCH(2)CH(2))(3)N](3-) ligand is replaced by a 2-mesitylpyrrolyl-alpha-methyl arm, that is, [(RNCH(2)CH(2))(2)NCH(2)(2-MesitylPyrrolyl)](3-) (R = C(6)F(5), 3,5-Me(2)C(6)H(3), or 3,5-t-Bu(2)C(6)H(3)). Compounds have been prepared that contain the lig...

Mo is widely used as an effective microalloying element to improve mechanical performance of interphase precipitation steels, but the precise role in behavior not fully understood. In this contribution, a series Ti-Mo-bearing low carbon steels systematically studied, and precipitates its coarsening revisited. It found that (Ti, Mo)C instead TiC are formed Mo-containing alloys, average site frac...

Heating K(4)Mo(2)Cl(8) and 2 equiv of Li[RC(NDipp)(2)] (R = H, Ph; Dipp = 2,6-i-Pr(2)C(6)H(3)) in tetrahydrofuran (THF) at 60 degrees C gives two paddlewheel type quadruply bonded dimolybdenum complexes, Mo(2)(mu-Cl)[Cl(2)Li(OEt(2))][mu-eta(2)-RC(N-2,6-i-Pr(2)C(6)H(3))(2)](2) (R = H (1), Ph (2)). The Mo-Mo bond lengths of 1 and 2 are 2.0875(4) and 2.0756(8) A, respectively, indicating typical M...

The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal-metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric mol-ecules in the unit cell (an inversion center is localized at the mid-point of the Mo-Mo bond), each with approximate non-crystallog...