Electrospinning has emerged as a facile technology for the synthesis of ultrafine fibers and even nanofibers of various materials. While carbon nanofibers have been extensively investigated, there have also been studies reported on metal oxide and metal carbide fibers. Yet, comparative studies, especially following the same general synthesis approach, are lacking. In our comprehensive study, we...

A route to prepare nitrides, such as GaN, VN, and other nitrides, is reported. The reaction pathway involves a two-step process by using the as-synthesized a-C3N3.69 as precursor. The route is so potent that a series of nitrides can be directly synthesized from their oxides at moderate temperatures. A striking feature of this method lies in that a-C3N3.69 is found to play double roles as both c...

During the synthesis of SiC, Si3N 4 and sialon whiskers by carbothermal reduction of SiO 2, a localized formation of amorphous phases or Si2N20 powders was observed beneath these whiskers. Because these whiskers were formed by the vapour/solid mechanism, the controlling gas phase was of primary importance to obtain whiskers of tailored morphology and chemistry. To elucidate the effect of the ga...

The present paper investigated the thermodynamics and kinetics of carbothermal reduction fayalite by non-isothermal method combining with thermogravimetric analyzer applying Flynn-Wall-Ozawa (FWO) M?lek models. According to thermodynamic analysis, starting temperature direct reaction was 806.79? in standard state. indirect could not take place While volume percentage CO higher than 86 vol.% non...

The effects of microwave plasma induction and reduction on the promotion of the carbothermal reduction of iron oxides (α-Fe2O3, γ-Fe2O3, and Fe3O4) are investigated using in situ emission spectroscopy measurements during 2.45 GHz microwave processing, and the plasma discharge (such as CN and N2) is measured during microwave E-field irradiation. It is shown that CN gas or excited CN molecules co...