CO2 is the primary anthropogenic greenhouse gas, accounting for 77% of the human contribution to the greenhouse effect in 2004. In the recent years, global concentration of CO2 in the atmosphere is increasing rapidly. CO2 emissions have an impact on global climate change. Anthropogenic CO2 is emitted primarily from fossil fuel combustion. Carbon capture and storage (CCS) is one option for reduc...

Mixed matrix membranes (MMMs) were fabricated by incorporating synthesized titanium dioxide (TiO2) nanoparticles into polyether block amide (PEBA) matrix to fabricate TiO2/PBEA MMMs for CO2/N2 separation. The mesoporous channels of TiO2 increased the density of active sites with high accessibility and also facilitate the diffusion of CO2 in the gas separation process. Furthermore, amine groups ...

New membrane types with well-controlled sub-nanostructures were developed from both polymeric and inorganic materials: carbon-based membranes, functionalized mesoporous oxide membranes and molecular sieving zeolite membranes. Regarding the carbon membranes, a novel carbon membrane with enhanced CO2 affinity was developed. The prepared membrane had a higher separation performance than that of th...

the performances of two-phase polymer-liquid pebax®/polyethylene glycol (peg) and three-phase polymer-liquid-solid pebax®/peg/mwnt thin film composite membranes for co2 and ch4 permeation were studied. the effect of temperature and mwnt/pebax® ratio on single gas (co2 and ch4) permeability was investigated. the permeation of both gases was measured at different temperatures from 303 to 323 ˚k. ...

The topic of global warming as a result of increased atomospheric CO2 concentration is becoming the most important environmental issue that the world faces today.[1] The capture and separation of CO2, especially CO2 from large point source, for example, fossil-fuel-fired electrical power–generation plants is critical to stabilize the atomospheric CO2 concentration.[2] The existing commercial CO...

In this study, an improved CO2 separation and purification system is proposed based on in-depth analyses of cryogenic separation and distillation theory as well as the phase transition characteristics of gas mixtures containing CO2. Multi-stage compression, refrigeration, and separation are adopted to separate the majority of the CO2 from the gas mixture with relatively low energy penalty and h...

Poly(amidoamine)s (PAMAMs) incorporated into a cross-linked poly(ethylene glycol) exhibited excellent CO2 separation properties over H2. However, the CO2 permeability should be increased for practical applications. Monoethanolamine (MEA) used as a CO2 determining agent in the current CO2 capture technology at demonstration scale was readily immobilized in poly(vinyl alcohol) (PVA) matrix by sol...

Efficient separation of acetylene (C2H2) from CO2 and CH4 is important to meet the requirement of high-purity acetylene in various industrial applications. Metal organic frameworks (MOFs) are great candidates for adsorption-based C2H2/CO2 and C2H2/CH4 separations due to their unique properties such as wide range of pore sizes and tunable chemistries. Experimental studies on the limited number o...

Growing evidence indicates that the CO2 emissions from the combustion of fossil fuels are contributing to global climate change. One indispensable approach to controlling CO2 emissions to the atmosphere is carbon capture, utilization and sequestration (CCUS) from large point sources, such as coal power plants. Membrane technology has emerged as an important separation technology for CO2 capture...

The world market for CO2/CH4 separation using membrane technology is getting bigger and polysulfone (PSf) is one of the most widely investigated polymer membrane materials. However, the existing PSf membranes performances are insufficient to fully exploit these opportunities. Therefore, modification that would produce membrane that fit the needs of target separation performances is a main issue...