Anion adsorption on the aluminum oxide, gibbsite, was investigated as a function of solution pH (3Y11) and equilibrium solution Mo (3.13, 31.3, or 313 Kmol/L), P (96.9 Kmol/L), or S (156 Kmol/L) concentration. Adsorption of all three anions decreased with increasing pH. Electrophoretic mobility measurements indicated a downward shift in point of zero charge, indicative of an inner-sphere adsorp...

Batch experiments were conducted in order to investigate the competitive interaction of arsenite (As(III)) and arsenate (As(V)) onto ferrihydrite as a function of initial pH, adsorbent dosage, concentration of coexisting ligands, and order of addition. The pH generally had a great impact on adsorption under both single ion and competitive conditions. However, the amount of As(V) in solution was...

We present a unique immobilization technique via physical adsorption/exchange of biomolecules onto a sensing surface of surface plasmon resonance (SPR). The adsorption/exchange is based on competitive bindings of biomolecules to a surface, which does not require a chemical modification of the biomolecules. SPR sensorgrams show that three human serum proteins, albumin, immunoglobulin G (IgG), an...

almcm-41 was applied for adsorption of methylene blue (mb) and auramine (au) in single and binary component systems. in the single component systems, almcm-41 represents higher adsorption capacity for mb than au with the maximal adsorption capacity of 2.07×10−4 and 1.15×10−4 mol/g at 25 ˚c for mb and au, respectively. in the binary component system, mb and au exhibit competitive adsorption onto...

Removal of Cd 2+ , Pb 2+ , and Ni 2+ from aqueous solutions using cellulosegraft-acrylic acid (C-g-AA) hydrogels was investigated. Various factors affecting the adsorption capacity, such as pH, time, initial ions concentration, and competitive ions, were tested. The results showed that the adsorption of hydrogels was very pH dependent, and maximum adsorption was obtained at a pH of 5.0. The ads...

Natural organic matter (NOM) is a major water constituent that affects the performance of drinking water treatment processes and the quality of drinking water. Besides, several studies have shown that NOM can be adsorbed on the surface of oxides being thereby able to compete with other ions. The overall goal of this study was essentially to investigate the competitive adsorption between fluorid...

The aim of this research is to quantify the competitive adsorption of a whey protein concentrate (WPC) and hydroxypropyl-methyl-cellulose (HPMC so called E4M, E50LV and F4M) at the air-water interface by means of dynamic surface tensiometry and Brewster angle microscopy (BAM). These biopolymers are often used together in many food applications. The concentration of both protein and HPMC, and th...

The competitive adsorption of human serum albumin (HSA), human immuno-gamma-globulin (HIgG) and human fibrinogen (HFb) onto polystyrene (PS) at 20 degrees C and a pH of 7.35 (phosphate-buffered saline) was studied. Protein adsorption was studied using enzyme immunoassay. The results obtained with the immunoassay were compared with those obtained using radiolabelled proteins. Recent studies reve...

The objective of this study was to compare the biological effects of two key cell-adhesive proteins, fibronectin (FN) and vitronectin (VN), upon adsorption onto molecularly-designed model surfaces. Single-component and mixed self-assembled monolayers (SAMs) of alkanethiols on gold with OH and CH(3) terminal groups were prepared at 100%, 65%, 36% and 0% of OH at the surface, to generate a range ...

plants uptake boron (b) from the soil solution, in which boron concentration is controlled by adsorption and desorption reactions on soil organic and inorganic colloids. considering the importance of aluminosilicate minerals in ion adsorption and desorption reactions in soil, in this research, b adsorption behavior on kaolinite was studied as a function of equilibrium concentration, ph, kaolini...