a novel quaternary ammonium-based cationic gemini surfactant (s6) having 1,6 di-bromo hexane as a spacer, have been used and its interaction with insulin in aqueous solution (ph, 7.40) was investigated by several methods including fluorescence spectroscopy, uv-vis spectroscopy, circular dichroism, dynamic light scattering, ζ-potential measurements, conductivity and transmission electron microsc...

New complexes of VO(II), Zn(II), Pd(II), Au(III) and Pt(IV) with atenolol (ATN) hypertensive drug ligand were synthesized and characterized by elemental analysis, conductometry, magnetic susceptibility, UV–Vis, IR, ESR, 1H-NMR spectroscopy, X-ray diffraction analysis of powdered samples, scanning electron microscopy (SEM), and thermal analysis. The IR spectral data suggested that the ATN ligand...

A complex of cerium(III) with 4-methyl-7-hydroxycoumarin was synthesized by mixing water solutions of cerium(III) nitrate and 4-methyl-7-hydroxycoumarin sodium salt in a metal-to-ligand molar ratio of 1:2. The complex was characterized and identified by elemental analysis, conductometry, IR, 1H and 13C NMR-spectroscopy, mass spectral data, DTA and TGA. Thermal analysis of the complex indicated ...

a new schiff base ligand, 2,2'-{pyridine-2,6-diylbis[nitrilo(e)methylylidene]}bis(4 bromophenol),has been synthesized by reaction of the 2,6-diamino pyridine with 5-bromo salicylaldehyde at ethanolunder refluxing. the structure of the synthesized compound resulted from the ir, 1hnmr, ms anduv spectroscopy and elemental analysis data. formation constant (kf) value of it’s complexes withcu2+, ni2...

Abstract To investigate the effect of cellulose matrix on diffusion and conductivity properties ionogels formed with BMIMCl ionic liquid (IL), two types samples were made micro (CMC) nano (CNC) cellulose. The interactions IL studied by 1 H 13 C NMR solid-state spectroscopy. cation [BMIM] + self-diffusion coefficient was calculated based Fast Field Cycling relaxation measurements. measured therm...

The reaction between NaAsO2 and oxalic acid was studied by pH-metric and conductometric measurements, applying the methods of continual variation and pH-metric and conductometric titration. It was found that oxalic acid forms a complex anion of the type [AsOC2O4]. The relative stability constant of the complex at ionic strengths, I, of 0.10 (log Kr = 4.70), 0.20 (log Kr = = 4.51), 0.50 (log Kr ...

A model of vesicle electrodeformation is described which obtains a parametrized vesicle shape by minimizing the sum of the membrane bending energy and the energy due to the electric field. Both the vesicle membrane and the aqueous media inside and outside the vesicle are treated as leaky dielectrics, and the vesicle itself is modeled as a nearly spherical shape enclosed within a thin membrane. ...

Critical micellar concentrations (CMCs) were determined for two novel promoters of membrane permeability – 7-monoketocholic acid (7-MKC) and 12monoketocholic acid (12-MKC), using two non-invasive (conductometry and H NMR relaxation experiment) methods. Studies by these methods suggest the different aggregation abilities of the investigated bile acid derivatives. In an aqueous solution, 7-MKC ha...