Control of EOF in microfluidic devices is essential in applications such as protein/DNA sizing and high-throughput drug screening. With the growing popularity of poly(methyl methacrylate) (PMMA) as the substrate for polymeric-based microfludics, it is important to understand the effect of surfactants on EOF in these devices. In this article, we present an extensive investigation exploring chang...

Nanoscopic and uniform unilamellar vesicles, rich in cholesterol, have been prepared using CO2-expanded solvents. This procedure is based on the depressurization of a cholesterol solution in CO2-expanded acetone into an aqueous solution containing a surfactant. The CO2 is used here as a co-solvent, allowing the straightforward preparation of vesicular systems with controlled size distribution, ...

Gold nanorods coated with cetyltrimethylammonium bromide (CTAB), a cationic micellar surfactant used in nanorod synthesis, were rapidly and irreversibly internalized by KB cells via a nonspecific uptake mechanism. Internalized nanorods near the cell surface were monitored by two-photon luminescence (TPL) microscopy and observed to migrate toward the nucleus with a quadratic rate of diffusion. T...

We provide a microscopic view of the role of halides in controlling the anisotropic growth of gold nanorods through a combined computational and experimental study. Atomistic molecular dynamics simulations unveil that Br(-) adsorption is not only responsible for surface passivation, but also acts as the driving force for CTAB micelle adsorption and stabilization on the gold surface in a facet-d...

Adsorption and desorption of sulfamethoxazole (SMX) at water-sediment interfaces from Taihu Lake, China, were investigated in this study. The effects of a cationic surfactant, cetyltrimethylammonium bromide (CTAB), and an anionic surfactant, sodium dodecylbenzene sulfonate (SDBS), on the adsorption/desorption processes were also studied. Results show that adsorption and desorption could be well...

In this research, effect of bicomponent mixed surfactant was studied on drop interface coalescence phenomenon in ambient temperature. First basic chemical system was water and toluene and 0.01 gr of sodium dodecyle sulfate (SDS) and the second basic system was water and toluene and 0.01 gr of cethyl trimethy amonium bromide (CTAB). Various weight fractions of second surfactant including 2-hepta...

the chemical surfactant flooding can mobilize the trapped oil by lowering the interfacial tension between oil and brine and in some cases altering the reservoir rock wettability. in this work, the effect of surfactants on oil/brine interfacial tension was experimentally investigated. first, the effect of surfactants concentration was surveyed. afterwards, the effect of salinity on surfactant be...

Catalytic and spectroscopic properties of alcohol dehydrogenase from horse liver, incorporated in reversed micellar media, have been studied. Two different reversed micellar systems have been used, one containing an anionic [sodium bis(2-ethylhexyl)sulfosuccinate, AOT], the other containing a cationic (cetyltrimethylammonium bromide, CTAB) surfactant. With 1-hexanol as substrate the turnover nu...

The physical properties of ionic surfactants are very sensitive to the nature of the counterions. In particular, counterions that have a tendency to adsorb on the surfactant micelle are known to dramatically modify the viscoelastic properties of these solutions through the formation of long wormlike micelles [1, 2, 3, 4]. One extreme limit of an adsorbed counterion is an oppositely charged surf...

In this research, the micellar behavior of a cationic surfactant, cetyl trimethyl ammonium bromide (CTAB) and an nonionic surfactant, polysorbate 20 (Polyoxyethylene (20) sorbitan monolaurate) in different alcohol solutions media was investigated over the temperature range 293.15-313.15 K. The interaction between two surfactants in binary systems can be determined by calculating the values of t...