Theoretical models of irreversible electro-oxidation of dissolved reactant giving dissolved product on the stationary planar electrode are developed for the conditions of staircase cyclic voltammetry. In the first model it is assumed that the product is adsorbed on the electrode surface and that the adsorbate prevents the transfer of electrons. In the second model it is assumed that the electro...

in this article, theoretical studies on the selective complexation of the halide ions (f¯, cl¯ and br¯) and ion pairs (na+f¯, na+cl¯ and na+br¯) with the cyclic nano-hexapeptide (cp) composed of l-proline have been performed in the gas phase. in order to calculate the dispersion interaction energies of the cp and ions, dft-d3 calculations at the m05-2x-d3/6-31g(d) level was employed. based on t...

5-((4-alkoxyphenyl)azo)salicyladehyde, 5-((4-alkoxyphenyl)azo)-N-(npentyl, ndodecyl)-salicyladimine and bis [5-((4-alkoxyphenyl)azo)-N-(npentyl, ndodecyl)-salicyladiminato]copper(II) [alkoxy=OnCnH2n+1; n=3-7] homologues were synthesized and characterized by elemental analyses, mass and IR spectra. All complex homol...

A novel chemically modified electrode containing Prussian blue complex was achieved on the surface of glass carbon electrode by sol-gel technique. The electrochemical behavior of modified electrode was characterized by cyclic voltammetry in detail. The film electrode obtained was very stable and exhibited electrocatalytic response for oxidation of nitrite. Results showed at bare GC electrode, a...

a novel ternary schiff base ligand (hl) of ono type and its copper (ii) complex weresynthesised using 2-aminophenol and o-acetoacetotoluidide. they have been characterised by theusual analytical and spectral methods. the interaction of the complex with calf-thymus (ct)dna has been investigated by uv-vis, viscosity measurement, cyclic voltammetry anddifferential pulse voltammetry studies. the re...

We show that an outer automorphism acts loxodromically on the cyclic splitting complex if and only if it has a filling lamination and no generic leaf of the lamination is carried by a vertex group of a cyclic splitting. This is the analog for the cyclic splitting complex of HandelMosher’s theorem on loxodromics for the free splitting complex. We also show that such outer automorphisms have virt...