Full recovery of interfacial bond strength after complete fiber/matrix debonding is achieved with a microencapsulated solvent-based healing chemistry. The surface of a glass fiber is functionalized with microcapsules containing varying concentrations of reactive epoxy resin and ethyl phenylacetate (EPA) solvent. Microbond specimens consisting of a single fiber and a microdroplet of epoxy are te...

Scaffolds were fabricated from poly-l-lactic acid (PLLA)/dicalcium phosphate dihydrate (DCPD) composite by indirect casting. Sodium citrate and PLLA were used to improve the mechanical properties of the DCPD scaffolds. The resulting PLLA/DCPD composite scaffold had increased diametral tensile strength and fracture energy when compared to DCPD only scaffolds (1.05 vs. 2.70 MPa and 2.53 vs. 12.67...

Introduction Self-healing materials are being developed to improve the lifetime of materials used in various applications including coatings, adhesives, structural components, and even microelectronics. The approach of using microencapsulation for self-healing has been particularly promising with proven success in coatings and in bulk epoxy. However, the size of microcapsules limits their use t...

The receptor molecules for human and animal hepatitis B viruses have not been defined. Previous studies have described a 170 to 180 kDa molecule (p170 or gp180) that binds in vitro to the pre-S domain of the large envelope protein of duck hepatitis B virus (DHBV); cDNA cloning revealed the binding protein to be duck carboxypeptidase D (DCPD). In the present study, the DCPD cDNA was transfected ...

In this study autonomic self-healing of impact damage in composite materials is shown using a microencapsulated healing agent. The components for self-healing, urea–formaldehyde microcapsules containing dicyclopentadiene (DCPD) liquid healing agent and paraffin wax microspheres containing 10 wt% Grubbs’ catalyst, have been successfully incorporated in a woven S2-glass-reinforced epoxy composite...

Successful arrest and retardation of fatigue cracks is achieved with an in situ self-healing epoxy matrix composite that incorporates microencapsulated dicyclopentadiene (DCPD) healing agent and Grubbs first generation Ru catalyst. Healing agent is released into the crack plane by the propagating crack, where it polymerizes to form a polymer wedge, generating a crack tip shielding mechanism. Du...

The aim of this paper is to develop a robust chemical process to synthesize Naand K-doped brushite (DCPD: dicalcium phosphate dihydrate, CaHPO4 2H2O), a potential starting material for bone substitutes. The powders were synthesized by using sodium phosphate and potassium phosphate and aqueous solutions containing calcium chloride at room temperature, followed by drying at 37°C. DCPD powders thu...

Virus-cell surface receptor interactions are of major interest. Hepadnaviruses are a family of partially double-stranded DNA viruses with liver tropism and a narrow host range of susceptibility to infection. At least in the case of duck hepatitis B virus (DHBV), host specificity seems controlled partly at the receptor level. The middle portion in the pre-S region of the viral large envelope pro...

The solubility isotherm for CaHPO4 • 2H2O (DCPD) in the three-component system Ca(OH)2 — H3PO4 — H2O was determined in the pH range 3.5 to 6.8 by leaching a thermostated column of DCPD with dilute phosphoric acid solutions. In confirmatory experiments, equilibrium was approached both from superand under-saturation by shaking DCPD with appropriate solutions. The calculated ionic activity product...