^ A continuously sampling, time-of-flight mass spectrometer has been used to measure relative species concentrations in a two-dimensional, hydrogen-air combustion wake at mainstream f; Mach numbers exceeding 5. The experiments»which were conducted in a free piston shock ! tunnel, yielded distributions of hydrogen, oxygen, nitrogen, water and nitric oxide at stagnation enthalpies ranging from 5....

In this work, polyamide (PA)/silica nanocomposite films prepared by dissolution method of composite mixing were investigated. The morphology of nanocomposite films were characterized using scanning electron microscope (SEM), reveals that nano silica powder were uniformly dispersed on PA silica nanocomposite film. Chemical composition of film was confirmed by Fourier transform infrared spectrosc...

We perform density-functional theory ~DFT! calculations of carbon dissolution and diffusion in iron, the latter being a typical example of interstitial diffusion. The Kohn-Sham equations are solved with periodic boundary conditions and within the projector-augmented-wave formalism, using the generalized gradient approximation for electron exchange and correlation. With the solution enthalpy as ...

Abstract Carbon capture and storage in underground formations might be considered as a relevant technology to curb anthropogenic climate gas emissions. However, carbon dioxide ( $${{\hbox {CO}}_{2}}$$ CO 2 ) injection can lead severe rock-fluid interactions depend...

The purpose of this study is to confirm the impact of polar functional groups on inter and intra-molecular hydrogen bonding in haloperidol (HP) and droperidol (DP) and, hence, their effects on dissolution using a new approach. To confirm our theory, a new molecule: deshydroxy-haloperidol (DHP) was designed and its synthesis was requested from a contract laboratory. The molecule was then studied...

The storage of gases in porous adsorbents, such as activated carbon and carbon nanotubes, is examined here thermodynamically from a systems viewpoint, considering the entire adsorption-desorption cycle. The results provide concrete objective criteria to guide the search for the "Holy Grail" adsorbent, for which the adsorptive delivery is maximized. It is shown that, for ambient temperature stor...

The reaction mechanisms by which antioxidants can exert their activity are: hydrogen atom transfer (HAT), proton coupled electron transfer (PCET), sequential proton loss electron transfer (SPLET), single electron transfer proton transfer (SET-PT), radical adduct formation, and sequential proton loss hydrogen atom transfer. The antioxidative activity of different compounds (flavones, flavonols, ...

On the basis of the thermokinetics of the hydrogen (deuterium) evolution reaction and the thermodynamics of Pd+H(D) system, we analytically and numerically discuss effects of temperature on the loading ratio of hydrogen (deuterium) absorption into electrodes of β-phase PdHx (PdDx) under the galvanostatic charging condition. It is found that the change of the loading ratio with temperature depen...