Poly(styrene-co-maleic anhydride)s were modified with poly(propylene oxide (PO)-co-ethylene oxide (EO)) side chains (Jeffamine) with different EO/PO molar ratios, varying between 0.11 and 3.60. These copolymers were then further functionalized with a β-mercapto ketone of δ-damascone. The obtained poly(maleic acid monoamide)-based β-mercapto ketones were then studied as delivery systems for the ...

Amphiphilic triblock copolymer, poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide), Pluronic P85, is unexpectedly shown to utilize sophisticated cellular trafficking mechanisms and enter brain microvessel endothelial cells and primary neurons that are poorly penetrable. Though caveolae serve as a primary entry site for the copolymer single chains, in cells devoid of caveolae, t...

In this work, we have conducted in situ simultaneous small- and wide-angle X-ray scattering Raman spectroscopy experiments to investigate the fundamental differences mechanism of mesomorphic α phase transition isotactic polypropylene homopolymer random ethylene–propylene copolymer. Via quantitative analysis results coming from three techniques, found that homopolymer, chain interlock extension ...

Previous studies have examined different strategies for siRNA delivery with varying degrees of success. These include use of viral vectors, cationic liposomes, and polymers. Several copolymers were designed and synthesized based on blocks of poly(ethylene glycol) PEG, poly(propylene glycol) PPG, and poly(l-lysine). These were designated as P1, P2, and P3. We studied the copolymer self-assembly,...

Size exclusion chromatography (SEC) is a technique routinely used at high temperature to analyze the molar mass distribution (MMD) in polymers. The of comonomer along axis copolymer key microstructural feature that determines macroscopic properties material and thus its range possible applications. However, unsaturated polymers requiring dissolution temperature, measurement chemical composition...

After blending the triblock copolymer, poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) (PEO-b-PPO-b-PEO) with novolac-type phenolic resin, Fourier transform infrared spectroscopy revealed that the ether groups of the PEO block were stronger hydrogen bond acceptors for the OH groups of phenolic resin than were the ether groups of the PPO block. Thermal curing with hexamethylenetetramine ...

The heating-induced micellization of poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) (Pluronic PE10300) triblock copolymer chains was studied by ultrasensitive differential scanning calorimetry, laser light scattering, and fluorescence spectrometry with a fluorescent probe, 8-anilino-1-naphthalenesulfonic acid ammonium salt. The critical micellization temperatures obtained f...

Gas permeability coefficients were obtained for CO2 and He gases at room temperature in a semicrystalline ethylene/ethylene–propylene/ ethylene (E/EP/E) triblock copolymer, and a blend of polyisoprene (PI) with an E/EP diblock copolymer. It was found that the gas transport properties of these polymer systems were influenced by changes in processing conditions and solvent treatments to create na...