The cascade reactions of 1-arenoylcyclopropanecarboxylic acids with arenes proceed smoothly in freshly distilled HOTf to give the corresponding tetrahydro-5H-benzo[c]fluorene derivatives in good yields along with high stereoselectivities under mild conditions.

This review summarizes our work in the field of synthesis natural products and their derivatives. Application modern synthetic method is discussed context syntheses both enantiomers hydromorphone, (–)-tetrodotoxin (a marine toxin), selaginpulvilins C D (natural fluorene derivatives). Further, notoincisol A, selagibenzophenones A B described to clarify structural aspects compounds. Last but not ...

A series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. The yields of the reactions depend on the kind of anion. Addition of 1-indeny anion to the iminium salt gives the amino derivative of 1-indene, while addition of fluo...

1. Reaction of 2-(N-acetoxy)-acetamidofluorene with orthophosphate buffer at pH7 yielded a large quantity of water-soluble fluorene derivatives, which showed absorption peaks at 303, 290 and 280nm. Tris buffer under similar conditions gave negligible reaction. 2. Hydrolysis of polar material with acid or alkaline phosphatases liberated equimolar amounts of inorganic phosphate and an ether-extra...

a series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. the yields of the reactions depend on the kind of anion. addition of 1-indeny anion to the iminium salt gives the amino derivative of 1-indene, while addition of fluo...

Crude oils and source rocks from the Northern and offshore depobelts of the Niger Delta basin, Nigeria have been characterized based on the distribution of pyrene and its derivatives by gas chromatography-mass spectrometry. Moreover, the crude oils have been characterized by the dominance of pyrene over fluoranthene while fluoranthene generally predominated over pyrene in the rock samples. Also...