We have studied charge injection across the metal/organic semiconductor interface in bottom-contact poly(3-hexylthiophene) (P3HT) field-effect transistors, with Au source and drain electrodes modified by self-assembled monolayers (SAMs) prior to active polymer deposition. By using the SAM to engineer the effective Au work function, we markedly affect the charge injection process. We systematica...

The redox properties of sulfite ion has been examind using cyclic voltammetry in acetonitrile solvent at the surface of gold, pelatin and glassy carbon electrodes. It has bben found tha, sulfite ion exhibits two electron oxidation peak with EC’ mechanism. A novel chemically modified electrode containing Prussian blue complex and multi wall carbon nanotubes (MWCNs) was achieved on the surface of...

In this paper, a sensitive chronocoulometric deoxyribonucleic acid (DNA) biosensor based on a nanostructure gold electrode was fabricated for detection of the femtomolar level survivin gene which was correlated with osteosarcoma by using hexaamine-ruthenium III complexes, [Ru(NH(3))(6)](3+), as the electrochemical indicator. The effect of different frequencies on the real surface area of the na...

0A thin film of cobalt hexacyanoferrate (CoHCF), an analogue of mixed-valence Prussian blue, was deposited electrochemically on the glassy carbon, platinum and gold electrode surfaces in 0.5M KC1 solution. The electrochemical behavior of these modified electrodes show three couples of redox peaks by CV in a supporting electrolyte solution of 0.5M NaCl, whereas for Au modified electrode only ...

A nanoporous gold film (NPGF) was prepared onto a gold electrode surface using a facile and green electrochemical approach via anodization at 2.0 V in 0.5 mol L(-1) H2SO4. The as-synthesized NPGF electrode showed superior electrocatalytic activity towards dissolved oxygen reduction at a low overpotential (-0.045 V) along with 2-fold enhanced sensitivity.

New and unknown electrocatalytic oxidation of water was found to occur on a nano-gold attached palladium electrode. Since the oxidation potential was negative enough to that of well-known normal oxidation of water to form O2, the direct use of water as a fuel, instead of alcohols, might be possible using the nano-gold/palladium electrode.

The direct reagentless electrochemical detection of recombinant firefly luciferase binding with gold electrode modified with nickel ions has been carried out. Self-assembly of molecules of functional disulfide containing chelating moieties on the gold electrode was monitored by contact angle measurements and confirmed by electrochemical data as three times decrease of electric double layer capa...

Selective modification of electrode surfaces is a vital step in the development of many practical applications of self-assembled monolayers (SAMs). This paper describes a protection-deprotection strategy similar to that commonly utilized in organic synthesis, with gold oxide as a protecting layer, to direct self-assembly on one gold electrode in the presence of another.

Citation: Han H, Pan D, Liu D, Hu X, Lin M and Li F (2015) Cathodic stripping voltammetric determination of chromium in coastal waters on cubic Nano-titanium carbide loaded gold nanoparticles modified electrode. Front. Mar. Sci. 2:75. doi: 10.3389/fmars.2015.00075 Cathodic stripping voltammetric determination of chromium in coastal waters on cubic Nano-titanium carbide loaded gold nanoparticles...

The redox properties of a monolayer of alkanethiolate-protected gold nanoclusters (MPCs) constructed on a gold slide electrode was studied in 1,2-dichloroethane (DCE) electrolyte solutions. The influence of the electrostatic interaction between attached MPCs and the substrate electrode on the absolute standard redox potential of MPCs was theoretically considered and studied experimentally.