In this article, a series of effective catalysts based on betaine and sulfuric or phosphomolybdic acids was obtained. These compositions were characterized by various physicochemical methods tested in the oxidation sulfur- nitrogenous-containing compounds H2O2. An increase amount heteropolyacid (HPA) leads to non-linear change acidity, degree removal sulfur-containing correlates with concentrat...

Omeprazole, (6-methoxy-2-((4-methoxy-3,5-dimethylpyridin-2-yl)methylsulfinyl)-1H-benzimidazole is a well-established prescribed drug, exhibits proton pump inhibitor activity. In this work, a novel, facile, economical and selective oxidation approach using H3PW12O40 as Keggin type heteropolyacids along with H2O2 in the ...

New rapid, sensitive and simple electrometric method was developed to determine sertraline hydrochloride (Ser-Cl) in its pure raw material and pharmaceutical formulations. Membrane sensors based on heteropolyacids as ion associating material were prepared. Silicomolybdic acid (SMA), silicotungstic acid (STA) and phosphomolybdic acid (PMA) were used. The slope and limit of detection are 50.00, 6...

The currently available PEMs are suitable for use at maximum 80C because of the requirement of the presence of water for proton conductivity. However, for emerging applications, a fuel cell operating at temperatures as high as 120 C is required. This can possibly be achieved by creating novel PEMs. Supramolecular polymers are being investigated extensively and may be conjugated with heteropolya...

Alcoholic solvents, especially methanol, show an activating affect for heteropolyacids in homogenously catalysed glucose transformation reactions. In detail, they manipulate the polyoxometalate-based catalyst a way that thermodynamically favoured total oxidation to CO2 can be completely supressed. This allows nearly 100 % carbon efficiency reaction of methyl formate methanolic solution at mild ...

Competitive reactions between C-labeled dimethyl ether (C-DME) and unlabeled alkenes have been used to examine the mechanistic details of chain growth and termination pathways leading to the selective formation of triptane and isobutane by means of the homologation of DME or methanol (Scheme 1). These studies have also provided specific and quantitative evidence for the ubiquitous role of carbe...