In this work, TiO2 /SiO2 (pure anatase), and TiO2 /SiO2 (anatase/rutile) nano-photocatalysts are prepared by using sol-gel method and control of acidity. The particles size is calculated using Scheerer, s equation and is estimated to be around 7-15 nm. In order to improve the photocatalytic activity of TiO2 /SiO2 ,1% (wt) platinum particles are loaded on both catalysts using photoreductive meth...

A series of bimetallic organo-group 4 "constrained geometry" catalysts and binuclear bisborane and bisborate cocatalysts have been synthesized to probe catalyst center-catalyst center cooperativity effects on olefin enchainment in homogenous olefin polymerization and copolymerization processes. Significant nuclearity effects are found versus mononuclear controls, and the effect can be correlate...

Au(i)/Y(iii) single chain nanoparticles (SCNPs) are potent homogenous, recyclable catalysts for the hydroamination. The SCNPs consist of terpolymer chains with orthogonal ligand units, enabling selective embedding different metals.

Amidoalkyl-2-naphthols as synthetic intermediates play an important role in medicinal chemistry due to their remarkable biological and many pharmacological properties. Owing to the versatile biological activities, industrial and synthetic applications of these compounds, introduction of an alternative methodology is urgent in synthetic organic chemistry. Low yield and harsh reaction conditions ...

H abitat change and invasions of alien species are usually listed as the two biggest causes of biodiversity loss. When the two coincide, the results can be devastating, because altered habitat often favors alien species adapted to the changed conditions. This is particularly true in streams and rivers of North America, where homogenization of fish faunas through extinction of native species and...

Amidoalkyl-2-naphthols as synthetic intermediates play an important role in medicinal chemistry due to their remarkable biological and many pharmacological properties. Owing to the versatile biological activities, industrial and synthetic applications of these compounds, introduction of an alternative methodology is urgent in synthetic organic chemistry. Low yield and harsh reaction conditions ...

b-Lactones are important intermediates for ring-opening polymerization to form poly(b-hydroxyalkanoates), a naturally occurring biodegradable and thermoplastic polyester. Many synthetic methods are available for preparing b-lactones, among which catalytic ring-opening carbonylation of epoxides has received considerable attention because of its ability to produce enantiopure b-lactones. Over the...

One of the challenges to utilize high performance III-V compound semiconductor nanowires (NWs) for large-scale technological applications is to control the crystal phase and growth orientation for homogenous nanowire properties. Here, we report the dependence of crystal structure and growth orientation of GaAs NWs on NixGay seeds via vapor-solid-solid mechanism. The crystal structure of catalyt...

Biofuels, as a renewable, eco-friendly, and cost-effective energy source, can reduce the dependence on fossil fuels. The researchers considered different approaches for obtaining high biodiesel yields from microalgae biomass. This work aims to present an overview of feasibility use in production. Therefore, production oil via transesterification process was explained detail. application non-cat...