Fatal hydrogen sulphide poisoning usually occurs in confined spaces. We report two fatal accidents in unconfined spaces. The first accident caused the death of three workers who entered an unconfined room in a silo of sludge at the same time that a truck dumped several tons of sludge from water purification stations. The hydrogen sulphide that had accumulated inside the silo spilled out into th...

Hydrogen sulphide production by growing cultures and non-multiplying suspensions was compared and the factors influencing the sensitivity of the tests were investigated. Cysteine hydrochloride (0.01 yo) was added to Lemco broth to provide a medium with a standard source of sulphur. H,S was detected with lead acetate papers more readily than by lead acetate agar. Suspensions were tested with cys...

During the reaction between 1,3,5-tris(2-hydroxyethyl)hexahydro-s-triazine and hydrogen sulphide, the principle by-product is the organic sulphide 5-(2-hydroxyethyl)dithiazine. It can be determined by a novel, portable, field-capable ion mobility spectrometry method described herein and enables the "degree spent" to be determined. Dependant upon the level of carbon dioxide in the produced gas, ...

The application of sulphide scavengers is a widely adopted practice in production and processing operations in the Oil and Gas Industry. Particularly challenging is the search and development of new chemistries, which is aimed at safeguarding the health of personnel and maintaining good protection of materials under a variety of conditions whilst being environmentally acceptable. This paper inc...

BACKGROUND/AIMS While the social significance of flatus derives mainly from its odour, previous studies have focused on the non-odoriferous components of rectal gas. The aims of the present study were to determine the role of sulphur-containing gases in flatus odour and test the efficacy of a device purported to reduce this odour. METHODS Flatus was quantitatively collected via rectal tube fr...

Whereas the compound formerly known as carvone hydrosulphide is, in fact, dicarvone sulphide [1], the genuine hydrosulphide, (—)-3-mercaptodihydrocarvone, has now been prepared by the addition of hydrogen sulphide to (—)-carvone in the presence of a base following a procedure analogous to that of van Tamelen and Grant [2]. Tt had boiling point 150-151 °/0.5 mm, ri&, 1.5221 [a]2i? —6.3° (c = 4 i...

The low-temperature environment of a free jet expansion provides an excellent laboratory for probing the conformational behaviour of hydrogen bonding. The first observation of axial and equatorial hydrogen-bonded complexes has been reported for tetrahydropyran and pentamethylene sulphide complexes with HCl and HF. Both six-membered rings present two nonequivalent lone pairs at the O or S atoms ...